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Fluorescence properties in different solvents and synthesis of axially substituted silicon phthalocyanine bearing bis-4-tritylphenoxy units
Heterocyclic Communications ( IF 2.3 ) Pub Date : 2020-10-15 , DOI: 10.1515/hc-2020-0113
Mehmet Salih Ağırtaş 1
Affiliation  

Abstract In this present study, a new axially bis-4-tritylphenoxy substituted silicon phthalocyanine compound was synthesized and characterized using infrared, mass, electronic absorption and nuclear magnetic resonance spectroscopy. Fluorescence and absorption spectra studies of the disubstituted silicon phthalocyanine complex were conducted on the chloroform, dimethyl formamide, dimethyl sulfoxide and tetrahydrofuran solutions. The findings of the fluorescence studies demonstrated that the compound has fluorescence spectra in the different solvents. The effects of the substitution with axially bis-4-tritylphenoxy functionalized groups on these parameters were also compared with the previously synthesized axially disubstituted silicon phthalocyanines. These results proved that the compound has different fluorescence properties in the different solvents.

中文翻译:

不同溶剂中的荧光特性及含双-4-三苯甲基苯氧基单元的轴向取代硅酞菁的合成

摘要 在本研究中,合成了一种新的轴向双-4-三苯甲基苯氧基取代的硅酞菁化合物,并使用红外、质谱、电子吸收和核磁共振光谱对其进行了表征。对氯仿、二甲基甲酰胺、二甲亚砜和四氢呋喃溶液进行了双取代硅酞菁配合物的荧光和吸收光谱研究。荧光研究结果表明该化合物在不同溶剂中具有荧光光谱。还将轴向双-4-三苯甲基苯氧基官能团取代对这些参数的影响与先前合成的轴向双取代硅酞菁进行了比较。
更新日期:2020-10-15
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