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Seasonal characteristics and sources of carbonaceous components and elements of PM10 (2010–2019) in Delhi, India
Journal of Atmospheric Chemistry ( IF 2 ) Pub Date : 2021-07-26 , DOI: 10.1007/s10874-021-09424-x
Sudhir Kumar Sharma 1, 2 , Rubiya Banoo 1, 2 , Tuhin Kumar Mandal 1, 2
Affiliation  

In this study we present the seasonal chemical characteristics and potential sources of PM10 at an urban location of Delhi, India during 2010˗2019. The concentrations of carbonaceous aerosols [organic carbon (OC), elemental carbon (EC), water soluble organic carbon (WSOC) and water insoluble organic carbon (WIOC)] and elements (Al, Fe, Ti, Cu, Zn, Mn, Pb, Cr, F, Cl, Br, P, S, K, As, Na, Mg, Ca, B, Ni, Mo, V, Sr, Zr and Rb) in PM10 were estimated to explore their possible sources. The annual average concentration (2010–2019) of PM10 was computed as 227 ± 97 µg m−3 with a range of 34˗734 µg m−3. The total carbonaceous aerosols in PM10 was accounted for 22.5% of PM10 mass concentration, whereas elements contribution to PM10 was estimated to be 17% of PM10. The statistical analysis of OC vs. EC and OC vs. WSOC of PM10 reveals their common sources (biomass burning and/or fossil fuel combustion) during all the seasons. Enrichment factors (EFs) of the elements and the relationship of Al with other crustal metals (Fe, Ca, Mg and Ti) of PM10 indicates the abundance of mineral dust over Delhi. Principal component analysis (PCA) extracted the five major sources [industrial emission (IE), biomass burning + fossil fuel combustion (BB + FFC), soil dust, vehicular emissions (VE) and sodium and magnesium salts (SMS)] of PM10 in Delhi, India. Back trajectory and cluster analysis of airmass parcel indicate that the pollutants approaching to Delhi are mainly from Pakistan, IGP region, Arabian Sea and Bay of Bengal.



中文翻译:

印度德里PM10(2010-2019)碳质组分和元素的季节特征和来源

在本研究中,我们展示了2010˗2019 年印度德里城市地区PM 10的季节性化学特征和潜在来源。含碳气溶胶 [有机碳 (OC)、元素碳 (EC)、水溶性有机碳 (WSOC) 和水不溶性有机碳 (WIOC)] 和元素 (Al、Fe、Ti、Cu、Zn、Mn、Pb) 的浓度、Cr、F、Cl、Br、P、S、K、As、Na、Mg、Ca、B、Ni、Mo、V、Sr、Zr 和 Rb)在 PM 10 中被估计以探索它们的可能来源。PM 10的年平均浓度(2010-2019)计算为 227 ± 97 µg m -3,范围为 34˗734 µg m -3。在下午的总碳气溶胶10被占PM的22.5%,10质量浓度,而元素对 PM 10 的贡献估计为 PM 10 的17% 。PM 10的 OCEC 和 OCWSOC的统计分析揭示了它们在所有季节的共同来源(生物质燃烧和/或化石燃料燃烧)。PM 10的元素富集因子 (EF) 以及 Al 与其他地壳金属(Fe、Ca、Mg 和 Ti)的关系表明德里上空矿尘的丰度。主成分分析 (PCA) 提取 PM 10的五个主要来源 [工业排放 (IE)、生物质燃烧 + 化石燃料燃烧 (BB + FFC)、土壤粉尘、车辆排放 (VE) 和钠和镁盐 (SMS)]在印度德里。气团返回轨迹和聚类分析表明,接近德里的污染物主要来自巴基斯坦、IGP地区、阿拉伯海和孟加拉湾。

更新日期:2021-07-27
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