Reticular frameworks including metal−organic frameworks (MOFs) and covalent organic frameworks (COFs), and their derived materials have drawn global attention in the capture and conversion of CO₂ as a cheap feedstock into fine chemicals and fuels due to their facile synthesis and programmable highly porous structures. This review comprehensively summarizes the progress in thermo−catalysis of CO₂ conversion by reticular framework−based catalysts to afford chemicals such as cyclic carbonates, cyclic carbamates, formamides, carboxylic acid, carbon monoxide, formate, methanol, methane, and light olefins. Firstly, the characteristics and advantages of MOF−based materials for CO₂ conversion are introduced. Secondly, the characteristics and advantages of COF−based materials for CO₂ conversion are presented. Subsequently, the CO₂ conversion reactions are briefly classified and discussed. Particularly, MOF or COF−based catalysts for each reaction are summarized in terms of catalyst design, catalytic performance and catalytic mechanism. Finally, the perspectives for further development of reticular framework−based catalysts for efficient CO₂ conversion are discussed. We hope this review can provide an inspiration for the rational design of porous crystalline materials for thermal catalytic CO₂ conversion.

包括金属有机骨架 (MOF) 和共价有机骨架 (COF) 在内的网状骨架及其衍生材料由于其易于合成和可编程性，在作为廉价原料的 CO ₂捕获和转化为精细化学品和燃料方面引起了全球关注高度多孔的结构。本综述全面总结了基于网状骨架的催化剂在热催化 CO ₂转化以提供化学物质如环状碳酸酯、环状氨基甲酸酯、甲酰胺、羧酸、一氧化碳、甲酸酯、甲醇、甲烷和轻质烯烃方面的进展。一、MOF基材料对CO ₂的特性和优势转换介绍。其次，介绍了基于COF 的CO ₂转化材料的特点和优势。随后，对 CO ₂转化反应进行了简要分类和讨论。特别是，从催化剂设计、催化性能和催化机理方面总结了每个反应的基于 MOF 或 COF 的催化剂。最后，讨论了进一步开发用于高效 CO ₂转化的网状框架催化剂的前景。我们希望这篇综述能为热催化CO ₂转化多孔晶体材料的合理设计提供启发。