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Stable carbon and nitrogen isotopic characteristics of PM2.5 and PM10 in Delhi, India
Journal of Atmospheric Chemistry ( IF 2 ) Pub Date : 2022-01-23 , DOI: 10.1007/s10874-022-09429-0
Sudhir Kumar Sharma 1 , Tuhin Kumar Mandal 1 , Supriya G. Karapurkar 2 , Damodar M. Shenoy 2
Affiliation  

This study presents the chemical composition (carbonaceous and nitrogenous components) of aerosols (PM2.5 and PM10) along with stable isotopic composition (δ13C and δ15N) collected during winter and the summer months of 2015–16 to explore the possible sources of aerosols in megacity Delhi, India. The mean concentrations (mean ± standard deviation at 1σ) of PM2.5 and PM10 were 223 ± 69 µg m−3 and 328 ± 65 µg m−3, respectively during winter season whereas the mean concentrations of PM2.5 and PM10 were 147 ± 22 µg m−3 and 236 ± 61 µg m−3, respectively during summer season. The mean value of δ13C (range: − 26.4 to − 23.4‰) and δ15N (range: 3.3 to 14.4‰) of PM2.5 were − 25.3 ± 0.5‰ and 8.9 ± 2.1‰, respectively during winter season whereas the mean value of δ13C (range: − 26.7 to − 25.3‰) and δ15N (range: 2.8 to 11.5‰) of PM2.5 were − 26.1 ± 0.4‰ and 6.4 ± 2.5‰, respectively during the summer season. Comparison of stable C and N isotopic fingerprints of major identical sources suggested that major portion of PM2.5 and PM10 at Delhi were mainly from fossil fuel combustion (FFC), biomass burning (BB) (C-3 and C-4 type vegitation), secondary aerosols (SAs) and road dust (SD). The correlation analysis of δ13C with other C (OC, TC, OC/EC and OC/WSOC) components and δ15N with other N components (TN, NH4+ and NO3) are also support the source identification of isotopic signatures.



中文翻译:

印度德里 PM2.5 和 PM10 的稳定碳氮同位素特征

本研究介绍了2015-16 年冬季和夏季月份收集的气溶胶(PM 2.5和 PM 10 )的化学成分(含碳和含氮成分)以及稳定同位素成分(δ 13 C 和 δ 15 N),以探索可能的印度特大城市德里的气溶胶来源。冬季PM 2.5和 PM 10的平均浓度(1σ 处的平均值±标准偏差)分别为 223 ± 69 µg m -3和 328 ± 65 µg m -3 ,而 PM 2.5和 PM 10的平均浓度为 147 ± 22 µg m -3和 236 ± 61 µg m -3,分别在夏季。PM 2.5的 δ 13 C(范围:- 26.4 至 - 23.4‰)和 δ 15 N(范围:3.3 至 14.4‰)在冬季分别为 - 25.3 ± 0.5‰ 和 8.9 ± 2.1‰夏季,PM 2.5的 δ 13 C(范围:- 26.7 至 - 25.3‰)和 δ 15 N(范围:2.8 至 11.5‰)的平均值分别为 - 26.1 ± 0.4‰ 和 6.4 ± 2.5‰。比较主要相同来源的稳定 C 和 N 同位素指纹表明 PM 2.5和 PM 10的主要部分在德里,主要来自化石燃料燃烧 (FFC)、生物质燃烧 (BB)(C-3 和 C-4 型植被)、二次气溶胶 (SAs) 和道路扬尘 (SD)。δ 13 C与其他C(OC、TC、OC/EC和OC/WSOC)组分的相关性分析和δ 15 N与其他N组分(TN、NH 4 +和NO 3 -)的相关性分析也支持了源识别。同位素特征。

更新日期:2022-01-23
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