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The Formation of a New Phase during Crystallization of TiO2-Doped Nd2O3-Al2O3-SiO2 Glasses
Transactions of the Indian Ceramic Society ( IF 1.2 ) Pub Date : 2022-03-30 , DOI: 10.1080/0371750x.2022.2044382
Saeid Baghshahi 1 , Charles Christopher Sorrell 2 , Michael Paul Brungs 3 , Hyung Sun Kim 4
Affiliation  

Glasses with the general compositions xNd 2O3.20Al2O3.(80–x)SiO2 and 15Nd2O3.yAl2O3.(85–y)SiO2 (x = 10, 15, 20, and y = 20, 25, 30) were prepared by melting at 1550°C. The glasses also contained varying amounts of TiO2 as nucleating agent. The microstructural evolution of the undoped and TiO2-containing glass-ceramics was then studied. Crystallization of the glasses was feasible in the range 1000° to 1250°C. The crystallization rates were evaluated. TiO2 addition influenced only the growth rate and not the nucleation of the crystalline phases observed in this study. Glasses of higher SiO2 content showed a rise in growth rate. It was found that when TiO2 was present, a new unreported crystalline compound with the stoichiometric composition of TiO2.Nd2O3.Al2O3.2SiO2 was formed



中文翻译:

TiO2掺杂Nd2O3-Al2O3-SiO2玻璃结晶过程中新相的形成

一般组成为xNd 2 O 3 .20Al 2 O 3 .(80–x)SiO 2和 15Nd 2 O 3 .yAl 2 O 3 .(85–y)SiO 2 (x = 10, 15, 20, and y = 20, 25, 30) 通过在 1550°C 熔融制备。该玻璃还含有不同量的TiO 2作为成核剂。然后研究了未掺杂和含有TiO 2的玻璃陶瓷的微观结构演变。玻璃的结晶在 1000° 至 1250°C 范围内是可行的。评价结晶速率。氧化钛添加仅影响生长速率,而不影响本研究中观察到的结晶相的成核。SiO 2含量较高的玻璃显示出生长速率的上升。发现当存在 TiO 2时,会形成一种新的未报道的结晶化合物,其化学计量组成为 TiO 2 .Nd 2 O 3 .Al 2 O 3 .2SiO 2

更新日期:2022-03-30
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