Three-dimensionally ordered macroporous (3DOM) materials have aroused tremendous interest in solar light to energy conversion, sustainable and renewable products generation, and energy storage fields owing to their convenient mass transfer channels, high surface area, enhanced interaction between matter and light, plentiful reactive sites as well as tunable composition. In this review, the state-of-the-art 3DOM materials as well as their preparation methods and the relevant applications including photo/electrocatalytic sustainable energy conversion, solar cells, Li ion batteries and supercapacitor are thoroughly outlined. Meanwhile, the unique merits and mechanisms for 3DOM materials in various applications are revealed and discussed in depth. Moreover, the strategies for designing 3DOM materials and the enhanced performance for applications are correlated, which can be significantly valuable to help readers to promptly acquire the comprehensive knowledge and to inspire some new ideas in developing 3DOM materials for further improved performances. Finally, the challenges and perspectives of 3DOM materials for sustainable energy conversion/production, solar cells and energy storage fields are outlooked. We sincerely look forward to that this critical review can facilitate the fast developments in designing highly efficient 3DOM materials and the relevant applications.

三维有序大孔（3DOM）材料由于其便捷的传质通道、高表面积、增强的物质与光之间的相互作用、丰富的等优点，在太阳能光能转换、可持续和可再生产品的生产以及储能领域引起了极大的兴趣。反应位点以及可调节的组成。在这篇综述中，对最先进的 3DOM 材料及其制备方法和相关应用，包括光/电催化可持续能源转换、太阳能电池、锂离子电池和超级电容器进行了详细概述。同时，对 3DOM 材料在各种应用中的独特优点和机制进行了深入的揭示和讨论。而且，3DOM 材料的设计策略和应用程序性能的增强是相关的，这对于帮助读者快速获得全面的知识并激发一些新的想法来开发 3DOM 材料以进一步提高性能具有重要价值。最后，展望了 3DOM 材料在可持续能源转换/生产、太阳能电池和储能领域的挑战和前景。我们真诚地期待这一批判性审查能够促进设计高效 3DOM 材料和相关应用的快速发展。展望了 3DOM 材料在可持续能源转换/生产、太阳能电池和储能领域的挑战和前景。我们真诚地期待这一批判性审查能够促进设计高效 3DOM 材料和相关应用的快速发展。展望了 3DOM 材料在可持续能源转换/生产、太阳能电池和储能领域的挑战和前景。我们真诚地期待这一批判性审查能够促进设计高效 3DOM 材料和相关应用的快速发展。