Metal anodes (Li, Na, K, Zn, Mg, Ca, Fe, Al, Mn, etc.) based on a plating/stripping electrochemical mechanism have attracted great attention in rechargeable batteries because of their low electrochemical potential, high theoretical specific capacity, and superior electronic conductivity. Metal anodes exhibit large potential in constructing high-energy-density rechargeable batteries. However, challenges such as high chemical reactivity, large volume changes, unstable solid electrolyte interphase (SEI), and uneven electrochemical deposition result in a serious of interfacial issues on metal anodes, including corrosion, side reaction, structural instability, and formation of dendrites. In the past several years, a lot of modification strategies based on interfacial engineering have been proposed to improve the interfacial stability of metal anodes. The interfacial engineering on metal anodes is mainly achieved by solid-liquid reaction, solid-solid reaction, solid-gas reaction, and physical decoration. In this review, we summary and analyze these interfacial engineering strategies on metal anodes in detail. Meanwhile, some perspectives and outlooks are put forward. This review can provide some enlightenment for related researchers and promote the development of metal anodes in rechargeable batteries.

基于电镀/剥离电化学机制的金属负极（Li、Na、K、Zn、Mg、Ca、Fe、Al、Mn 等）因其低电化学势、高理论比容量而在可充电电池中引起了广泛关注。 , 和优越的电子导电性。金属阳极在构建高能量密度可充电电池方面表现出巨大的潜力。然而，高化学反应性、大体积变化、不稳定的固体电解质界面（SEI）和不均匀的电化学沉积等挑战导致金属负极上的严重界面问题，包括腐蚀、副反应、结构不稳定和枝晶的形成。在过去的几年中，已经提出了许多基于界面工程的改性策略来提高金属负极的界面稳定性。金属阳极的界面工程主要通过固-液反应、固-固反应、固-气反应和物理修饰来实现。在这篇综述中，我们详细总结和分析了这些金属阳极的界面工程策略。同时，提出了一些观点和展望。本综述可以为相关研究人员提供一些启示，促进可充电电池金属负极的发展。