With the excessive consumption and dependence on non-renewable energy, it is urgent to seek sustainable clean energy. Using solar energy to yield target product is one of the main ways to solve environmental pollution and produce renewable resources. Conjugated porous polymers (Covalent organic frameworks, COFs. Conjugated microporous polymers, CMPs) could effectively convert solar energy into products due to their pre-designable structures and tailor-made functions. In this review, we overview the development of fundamental catalytic mechanisms, structural design principles, and summary of the advantages and progress of semi-conductive COFs/CMPs based on diverse building blocks (porphyryl-, pyrenyl-, carbazolyl-, triazinyl-, thienyl/thiazolyl-, β-ketoenamine-, conjugated alkenyl/alkynyl-, fluorenyl-), and outline the advances in COFs/CMPs as a universal platform for photocatalysts in a wide range of photocatalytic hydrogen evolution, carbon dioxide reduction, degradation of pollutions, nitrogen fixation, and organic conversion. We wish that this review will provide a comprehensive overview of photocatalysis, and boost the progress of conjugated porous polymers.

随着过度消费和对不可再生能源的依赖，寻求可持续的清洁能源迫在眉睫。利用太阳能生产目标产品是解决环境污染和生产可再生资源的主要途径之一。共轭多孔聚合物（共价有机框架，COFs。共轭微孔聚合物，CMPs）由于其可预先设计的结构和量身定制的功能，可以有效地将太阳能转化为产品。在这篇综述中，我们概述了基本催化机制的发展、结构设计原则，并总结了基于不同结构单元（卟啉基、芘基、咔唑基、三嗪基、噻吩基）的半导体 COF/CMP 的优势和进展。 /噻唑基-，β-ketoenamine-, conjugated alkenyl/alkynyl-, fluorenyl-), 并概述了 COFs/CMPs 作为光催化剂在广泛的光催化析氢、二氧化碳还原、污染降解、固氮和有机转换。我们希望这篇综述能够提供光催化的全面概述，并促进共轭多孔聚合物的进展。