Metal-organic frameworks (MOFs) show great promise for electrochemical energy storage applications due to their high surface area, tunable porosity, ordered crystal structure, and facile tolerability. However, some MOFs with high electrochemical performance are usually unstable in aqueous solutions, which limits their development in aqueous electrochemical energy storage systems, which are cheaper, safer, and more ionically conductive than those operating in conventional organic electrolytes. Numerous efforts have been made to construct stable MOFs or control MOF derivation processes induced by chemical or thermal forces to optimize their properties and performance. Therefore, a review summarizing the MOFs applied in aqueous electrochemical energy storage devices would be useful. In this review, the chemical stability and thermal stability of MOFs under aqueous conditions are discussed. The evolution processes of MOFs when they exceed their stability are summarized. Furthermore, the recent fast-growing literature on MOF-based aqueous ion batteries and supercapacitors is comprehensively reviewed, and guidelines for designing high-performance aqueous electrochemical devices are provided. The current challenges and opportunities for applying MOFs in aqueous electrochemical energy-storage devices are provided. We hope this review will promote the development of MOFs in aqueous electrochemical devices by exploiting the advantages and remedying the disadvantages of MOFs.

金属有机框架（MOFs）由于其高表面积、可调节的孔隙率、有序的晶体结构和容易的耐受性，在电化学储能应用中显示出巨大的前景。然而，一些具有高电化学性能的 MOFs 通常在水溶液中不稳定，这限制了它们在水系电化学储能系统中的发展，这些系统比在传统有机电解质中运行的那些更便宜、更安全、更具离子导电性。已经做出了许多努力来构建稳定的 MOF 或控制由化学或热力诱导的 MOF 衍生过程，以优化它们的性能和性能。因此，总结在水性电化学储能装置中应用的 MOF 将是有用的。在本次审查中，讨论了MOFs在水性条件下的化学稳定性和热稳定性。总结了MOFs超过稳定性时的演化过程。此外，对近期快速增长的关于 MOF 基水系离子电池和超级电容器的文献进行了全面回顾，并提供了设计高性能水系电化学装置的指南。提供了在水系电化学储能装置中应用 MOF 的当前挑战和机遇。我们希望这篇综述能够通过利用 MOFs 的优势和弥补 MOFs 的缺点来促进 MOFs 在水系电化学装置中的发展。全面回顾了最近快速增长的关于 MOF 基水系离子电池和超级电容器的文献，并提供了设计高性能水系电化学装置的指南。提供了在水系电化学储能装置中应用 MOF 的当前挑战和机遇。我们希望这篇综述能够通过利用 MOFs 的优势和弥补 MOFs 的缺点来促进 MOFs 在水系电化学装置中的发展。全面回顾了最近快速增长的关于 MOF 基水系离子电池和超级电容器的文献，并提供了设计高性能水系电化学装置的指南。提供了在水系电化学储能装置中应用 MOF 的当前挑战和机遇。我们希望这篇综述能够通过利用 MOFs 的优势和弥补 MOFs 的缺点来促进 MOFs 在水系电化学装置中的发展。