The conversion of sun light energy into sustainble greener chemicals are a major obstacle due to the use of expensive and toxic materials. Sun light induced trifluoromethylation emerges as a highly efficient procedure to insert trifluoromethyl groups into the organic compounds. Yet, the expensive and toxic properties of the metal-based photocatalysts creates a major obstacle for the insertion of trifluoromethyl groups. Metal free activated carbon cloth (ACC) emerged as a highly efficient pillar in the area of material science. In this work, we have successfully synthesized self-assembled metal free fast green with activated carbon cloth ([email protected]) photocatalyst for photocatalytic trifluoromethylation and reduced nicotinamide adenine dinucleotide (NADH) cofactor regeneration (85.89 %, 2 h) under sun light. The sun light induced organic transformation promotes the use of low-cost CF3SO2Na as the CF3 radical source to produce highly selective products with 97% yield.

中文翻译：

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易于制作高效的 FG@ACC 稳定平台，用于在阳光下生成 sp 3C-CF 3 键和 NADH 再生

由于使用昂贵且有毒的材料，将太阳能转化为可持续的绿色化学品是一个主要障碍。阳光诱导的三氟甲基化是一种将三氟甲基插入有机化合物的高效方法。然而，金属基光催化剂的昂贵和有毒特性为三氟甲基的插入造成了主要障碍。无金属活性炭布 (ACC) 成为材料科学领域的高效支柱。在这项工作中，我们成功地合成了自组装无金属固绿活性炭布 ([email protected]) 光催化剂，用于在阳光下光催化三氟甲基化和还原烟酰胺腺嘌呤二核苷酸 (NADH) 辅因子再生 (85.89 %, 2 h)。