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Green carbon dots from poppy seeds with conjugated hydrogel hybrid films for detection of Fe3+
Indian Journal of Chemical Technology ( IF 0.5 ) Pub Date : 2023-01-27
Ayşe GülÖzdil, Yusuf Özcan

A simple, non-toxic and eco-friendly method has been developed for detection of Fe3+ using the beneficial plant Opium Poppy (Papaver somniferum) seeds as a carbon source to fabricate a hybrid film (HF). The hybrid film platform comprises of quince seed mucilage and sodium alginate to form a fluorescent hybrid film with green carbon dots derived from poppy seeds (P-CDs). All materials and methods contain non-toxic chemicals. The prepared samples have been characterized morphologically, structurally and optically by spectroscopic techniques. A hydrodynamic radius of the P-CDs is determined as an average of 4.79 nm using Dynamic Light Scattering (DLS). It has been identified that hybrid film is selective towards Fe3+ ions among different metal ions with one-step by the naked-eye and turn-off detection and selectivity of P-CDs to Fe3+ is determined by fluorescence measurement. The detection limit (LOD) of Fe3+ ion is found as 0.356 mM. Developments of such a hybrid material from sustainable and low-cost sources make it an interesting option as a detection material must be investigated in various fields. For the first time, quince seed mucilage combined with green carbon dots and it has been studied in the detection field as a hybrid film. This study has proven that biotechnological studies about carbon dots can also obtain efficient results by providing green, economic, energy and water saving approaches.

中文翻译:

罂粟种子绿色碳点与共轭水凝胶杂化膜检测 Fe3+

使用有益植物罂粟 (Papaver somniferum) 种子作为碳源来制造混合膜 (HF),开发了一种简单、无毒且环保的检测 Fe3+ 的方法。混合膜平台由榅桲种子粘液和海藻酸钠组成,形成荧光混合膜,其中绿色碳点来自罂粟种子 (P-CD)。所有材料和方法都含有无毒化学物质。制备的样品已通过光谱技术在形态、结构和光学上进行了表征。使用动态光散射 (DLS) 确定 P-CD 的流体动力学半径平均值为 4.79 nm。已经通过肉眼和关闭检测一步鉴定杂化膜对不同金属离子中的Fe3+离子具有选择性,并且P-CDs对Fe3+的选择性通过荧光测量确定。发现 Fe3+ 离子的检测限 (LOD) 为 0.356 mM。从可持续和低成本来源开发这种混合材料使其成为一个有趣的选择,因为必须在各个领域研究检测材料。首次将榅桲种子粘液与绿色碳点结合,作为杂化薄膜在检测领域进行了研究。该研究证明,关于碳点的生物技术研究也可以通过提供绿色、经济、节能和节水的途径获得有效的结果。从可持续和低成本来源开发这种混合材料使其成为一个有趣的选择,因为必须在各个领域研究检测材料。首次将榅桲种子粘液与绿色碳点结合,作为杂化薄膜在检测领域进行了研究。该研究证明,关于碳点的生物技术研究也可以通过提供绿色、经济、节能和节水的途径获得有效的结果。从可持续和低成本来源开发这种混合材料使其成为一个有趣的选择,因为必须在各个领域研究检测材料。首次将榅桲种子粘液与绿色碳点结合,作为杂化薄膜在检测领域进行了研究。该研究证明,关于碳点的生物技术研究也可以通过提供绿色、经济、节能和节水的途径获得有效的结果。
更新日期:2023-01-28
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