Theoretical and Experimental Chemistry ( IF 1 ) Pub Date : 2023-02-15 , DOI: 10.1007/s11237-023-09748-7 N. V. Konoshchuk , O. Yu. Posudievsky , O. P. Rozovik , V. G. Koshechko , V. D. Pokhodenko
For the first time, the possibility of a CsPbBr3/h-BN nanocomposite preparing by a mechanochemical treatment of a dry mixture of PbBr2 and a hexagonal boron nitride delaminated with cesium bromide has been demonstrated. X-ray diffraction and electron microscopy studies show that the use of this method leads to the formation of crystalline CsPbBr3 nanosheets. Unlike to the mechanochemically synthesized individual CsPbBr3, the CsPbBr3/h-BN nanocomposite is characterized by bright green luminescence. The nanocomposite has enhanced resistance to air moisture and sunlight due to the presence of a hydrophobic thermally conductive layers of boron nitride.
中文翻译:
机械化学法获得的纳米复合材料 CsPbBr3/h-BN 的结构和光学性质
首次证明了通过机械化学处理 PbBr 2和用溴化铯分层的六方氮化硼的干混合物制备 CsPbBr 3 /h-BN 纳米复合材料的可能性。X 射线衍射和电子显微镜研究表明,使用这种方法可以形成结晶 CsPbBr 3纳米片。与机械化学合成的单个 CsPbBr 3不同,CsPbBr 3 /h-BN 纳米复合材料以亮绿色发光为特征。由于氮化硼的疏水导热层的存在,纳米复合材料增强了对空气湿气和阳光的抵抗力。