The dichloro-dioxide-(4,4′-dimethyl-2,2′-bipyridyl)-molybdenum (VI) complex was prepared from molybdenum(VI)-dichloride-dioxide and 4,4′-dimethyl-2,2′-bipyridyl in CH2Cl2 obtaining a clear green solution. The molybdenum complex was precipitated using ethyl ether, separated by filtration and the light green solid washed with ethyl ether. The XRPD pattern for the new compound showed that the crystalline compound belongs to the monoclinic space group P21/n (No.14) with refined unit-cell parameters a = 12.0225(8) Å, b = 10.3812(9) Å, c = 11.7823(9) Å, β = 103.180(9)°, unit-cell volume V = 1431.79 Å3, and Z = 4.

二氯二氧化-(4,4'-二甲基-2,2'-联吡啶)-钼(VI)络合物由二氧化钼(VI)-二氯化物和4,4'-二甲基-2,2'-制备联吡啶在CH 2 Cl 2中，得到澄清的绿色溶液。使用乙醚沉淀钼络合物，通过过滤分离并用乙醚洗涤浅绿色固体。新化合物的XRPD图谱表明该晶体化合物属于单斜晶系空间群P 2 1 / n (No.14)，其晶胞参数为a = 12.0225(8) Å, b = 10.3812(9) Å，c = 11.7823(9) Å, β = 103.180(9)°, 晶胞体积V= 1431.79 Å 3，Z = 4。