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Glass transition temperature of low-activity waste nuclear glasses
International Journal of Applied Glass Science ( IF 2.1 ) Pub Date : 2023-03-08 , DOI: 10.1111/ijag.16629
Jaime L. George 1 , Pavel Ferkl 1 , Jose Marcial 1 , Tongan Jin 1 , Pavel Hrma 2 , Albert A. Kruger 3
Affiliation  

The glass transition temperature (Tg) is a parameter used in many glass melt viscosity models as it denotes a temperature around which liquid-glass transition occurs. In this work, Tg values were measured for a series of low-activity waste (LAW) glasses using differential scanning calorimetry. These data were combined with Tg data of other waste glasses available from literature. The combined dataset, consisting of 137 data points, was used for the development of several models to estimate Tg from glass composition. When testing the number of influential components and different supervised learning methods, we demonstrated that using more than 10 components or using non-linear methods brought marginal improvement to the model accuracy. The best model predicts Tg of both LAW and high-level waste glasses with reasonable accuracy.

中文翻译:

低活度废核玻璃的玻璃化转变温度

玻璃化转变温度 ( T g ) 是许多玻璃熔体粘度模型中使用的参数,因为它表示发生液体-玻璃化转变的温度。在这项工作中,使用差示扫描量热法测量了一系列低活性废 (LAW) 玻璃的T g值。这些数据与文献中提供的其他废玻璃的Tg数据相结合。由 137 个数据点组成的组合数据集用于开发多个模型以估计T g从玻璃成分。在测试有影响的组件数量和不同的监督学习方法时,我们证明了使用超过 10 个组件或使用非线性方法对模型精度带来边际改进。最好的模型以合理的精度预测LAW和高级废玻璃的Tg 。
更新日期:2023-03-08
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