Theoretical and Experimental Chemistry ( IF 1 ) Pub Date : 2023-04-01 , DOI: 10.1007/s11237-023-09757-6 O. O. Pariiska , D. O. Mazur , V. M. Asaula , V. V. Buryanov , R. Socha , Ya.I. Kurys , S. V. Kolotilov , V. G. Koshechko , V. D. Pokhodenko
It has been found that composites based on Co,N,S-doped carbon and Co9S8 can act as catalysts for the hydrogenation of quinoline and its monomethyl derivatives providing the formation of 1,2,3,4-tetrahydroquinolines with 75-99% yields. The high efficiency of these systems is caused first of all with the presence of Co-Nx sites in their composition, which are formed as a result of the pyrolysis of cobalt salts and poly-5-aminoindole. The use of highly dispersed Vulcan XC72R carbon black as a component of the reaction mixture during the composite catalyst preparation by the pyrolysis contributes to a greater extent to the formation of active Co-Nx sites in them, compared to graphene oxide or in the case when a carbon component is not added.
中文翻译:
基于Co、N、S掺杂碳和Co9S8的纳米复合材料结构对喹啉及其甲基衍生物加氢过程中催化性能的影响
已经发现,基于 Co,N,S 掺杂的碳和 Co 9 S 8的复合材料可以作为喹啉及其单甲基衍生物氢化的催化剂,提供 1,2,3,4-四氢喹啉与 75- 99% 的收益率。这些系统的高效率首先是由于其组成中存在 Co-N x位点,这些位点是钴盐和聚 5-氨基吲哚热解的结果。在通过热解制备复合催化剂期间,使用高度分散的 Vulcan XC72R 炭黑作为反应混合物的组分,有助于更大程度地形成活性 Co-N x与氧化石墨烯或未添加碳成分的情况相比,它们中的位点。