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Physical and Chemical Investigation of TiO2 Nanotubes Treated with Isopropyl Triisostearoyl Titanate (KR-TTS)
Journal of Nanomaterials ( IF 3.791 ) Pub Date : 2023-4-28 , DOI: 10.1155/2023/7961857
Ban Ali Sabri 1 , Meenaloshini Satgunam 2 , A. Manap 3 , Constance L. Gnanasagaran 4 , Karthikeyan Ramachandran 4
Affiliation  

The aim of this study is to investigate the effect of isopropyl triisostearoyl titanate (KR-TTS) as a titanate coupling agent (TCA) on surface modification of TiO2 nanotube (TNT) material. From the physical and chemical studies that have been performed on the modified TiO2 nanotube, scanning electron microscope micrographs, energy-dispersive X-ray and viscosity indicated that there was significant reduction in particle aggregation of the modified TiO2 Nanotube. FTIR spectroscopy confirmed that the functional group of the TCA reacted with the hydroxyl groups present on the surface of TiO2 nanotube resulting in an altered surface property from being hydrophilic to hydrophobic. X-ray diffraction indicated that crystalline structure did not change upon the modification with the coupling agent. Isopropyl triisostearoyl titanate (KR-TTS) is found to be superior in performance and has a significant effect on the dispersion and resolving of agglomeration. This paper presents the effect of surface modification with the TCA of isopropyl triisostearoyl titanate (KR-TTS) type on the TiO2 nanotube material.

中文翻译:

三异硬脂酰钛酸异丙酯 (KR-TTS) 处理的 TiO2 纳米管的物理和化学研究

本研究的目的是研究三异硬脂酰钛酸异丙酯 (KR-TTS) 作为钛酸酯偶联剂 (TCA) 对 TiO 2纳米管 (TNT) 材料表面改性的影响。根据对改性 TiO 2纳米管进行的物理和化学研究,扫描电子显微镜显微照片、能量色散 X 射线和粘度表明改性 TiO 2纳米管的颗粒聚集显着减少。FTIR 光谱证实 TCA 的官能团与 TiO 2表面存在的羟基发生反应纳米管导致表面特性从亲水变为疏水。X射线衍射表明晶体结构在用偶联剂改性后没有改变。发现三异硬脂酰钛酸异丙酯 (KR-TTS) 性能优越,对团聚的分散和解决具有显着效果。本文介绍了用三异硬脂酰钛酸异丙酯 (KR-TTS) 型 TCA 对 TiO 2纳米管材料进行表面改性的效果。
更新日期:2023-04-29
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