当前位置: X-MOL 学术Sens. Actuators Rep. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Nanocrystalline ZnO quantum dot-based chemiresistive gas sensors: Improving sensing performance towards NO2 and H2S by optimizing operating temperature
Sensors and Actuators Reports Pub Date : 2023-06-03 , DOI: 10.1016/j.snr.2023.100166
Dung Thi Hanh To , Park Ji Young , Yang Bingxin , Nosang V. Myung , Yong-Ho Choa

Nanocrystalline ZnO quantum dots (QD) with a diameter of 10 nm was synthesized and tested toward eight different toxic industrial chemicals (i.e., nitrogen dioxide (NO2), hydrogen sulfide (H2S), ammonia (NH3), carbon monoxide (CO), methane (CH4), ethanol (C2H5OH), acetone (CH3)2CO, and toluene (C6H5CH3)) with a broad concentration range at five different operating temperatures. Systemic studies allow to determine the kinetics of gas sensing as well as the competing reactions of analytes with sensing material and adsorbed oxygen. ZnO QD showed an excellent sensing performance toward NO2 and H2S in comparison to other target analytes. The selectivity can be further improved by controlling the operating temperature (i.e., higher selectivity toward NO2 and H2S were achieved at 300 °C and 450 °C, respectively). Moreover, the optimal temperature was found to be analyte dependent.



中文翻译:

基于纳米晶 ZnO 量子点的化学阻性气体传感器:通过优化工作温度提高对 NO2 和 H2S 的传感性能

合成了直径为 10 nm 的纳米晶 ZnO 量子点 (QD),并针对八种不同的有毒工业化学品(即二氧化氮(NO 2 )、硫化氢 (H 2 S)、氨 (NH 3 )、一氧化碳 ( CO)、甲烷(CH 4 )、乙醇(C 2 H 5 OH)、丙酮(CH 3 ) 2 CO、甲苯(C 6 H 5 CH 3)) 在五种不同的工作温度下具有广泛的浓度范围。系统研究可以确定气体传感的动力学以及分析物与传感材料和吸附氧的竞争反应。与其他目标分析物相比, ZnO QD 对 NO 2和 H 2 S表现出出色的传感性能。通过控制操作温度可以进一步提高选择性(分别在 300 °C 和 450 °C 时实现对 NO 2和 H 2 S 的更高选择性)。此外,发现最佳温度取决于分析物。

更新日期:2023-06-07
down
wechat
bug