The N-heterocyclic stannylene [Fe{(η 5-C5H4)NC6H3-2,6-iPr2}2Sn] (1) has been synthesised from SnCl2 and the lithium amide [Fe{(η 5-C5H4)NC6H3-2,6-iPr2}2Li2]. Compound 1 is inert towards H2, CO, CO2, and MeI under ambient conditions. Immediate hydrolysis and ammonolysis was observed with H2O and NH3, respectively. While oxidation reactions of 1 with chalcogens (O2, S8, Se8) afforded only intractable material, the reaction with Ph2Se2 cleanly furnished [Fe{(η 5-C5H4)NC6H3-2,6-iPr2}2Sn(SePh)2] (2). Compounds 1 and 2 have been structurally characterised by single-crystal X-ray diffraction. Compound 2 exhibits an intramolecular CH⋯Se contact compatible with a weak hydrogen bond.

中文翻译：

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基于二茂铁的 N-杂环亚锡烯 [Fe{(η 5-C5H4)NC6H3-2,6-iPr2}2Sn] 的合成、结构和反应性

N-杂环亚锡烯[Fe{(η 5个-C5个H4个)数控6个H3个-2,6-我压力2个}2个Sn] (1) 由 SnCl合成2个和氨基化锂[Fe{(η 5个-C5个H4个)数控6个H3个-2,6-我压力2个}2个李2个]. 化合物 1 对 H 呈惰性2个, 一氧化碳, 一氧化碳2个和 Mel 在环境条件下。用 H 观察到立即水解和氨解2个O和NH3个， 分别。虽然 1 与硫属元素 (O2个, 小号8个, 硒8个) 只提供难处理的材料，与 Ph 的反应2个硒2个干净整洁的 [Fe{(η 5个-C5个H4个)数控6个H3个-2,6-我压力2个}2个锡(硒)2个] (2). 化合物 1 和 2 的结构已通过单晶 X 射线衍射进行了表征。化合物 2 表现出与弱氢键相容的分子内 CH⋯Se 接触。