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Measurement of CO2 adsorption capacity with respect to different pressure and temperature in sub-bituminous: implication for CO2 geological sequestration
Frontiers of Earth Science ( IF 2 ) Pub Date : 2023-06-09 , DOI: 10.1007/s11707-022-1026-x
Sijian Zheng , Shuxun Sang , Shiqi Liu , Meng Wang , Lutong Cao , Xin Jin , Guangjun Feng , Yi Yang

CCUS (carbon capture, utilization, and storage) technology is regarded as a bottom method to achieve carbon neutrality globally. CO2 storage in deep coal reservoirs serves as a feasible selection for CCUS, and its storage potential can be attributed to the CO2 adsorption capacity of the coal. In this paper, a series of CO2 adsorption isotherm experiments were performed at different pressures and temperatures in sub-bituminous coal from the southern Junggar Basin (reservoir temperature ∼25.9°C and pressure ∼3.91 MPa). In addition, the high-pressure CO2 adsorption characteristics of the southern Junggar Basin coal were characterized using a supercritical D-R adsorption model. Finally, the CO2 storage capacities in sub-bituminous coal under the in situ reservoir temperature and pressure were analyzed. Results indicated that the excess adsorption capacities increase gradually with increasing injection pressure before reaching an asymptotic maximum magnitude of ∼34.55 cm3/g. The supercritical D-R adsorption model is suitable for characterizing the excess/absolute CO2 adsorption capacity, as shown by the high correlation coefficients > 0.99. The CO2 adsorption capacity increases with declining temperature, indicating a negative effect of temperature on CO2 geological sequestration. By analyzing the statistical relationships of the D-R adsorption fitting parameters with the reservoir temperature, a CO2 adsorption capacity evolution model was established, which can be further used for predicting CO2 sequestration potential at in situ reservoir conditions. CO2 adsorption capacity slowly increases before reaching the critical CO2 density, following a rapid decrease at depths greater than ∼800 m in the southern Junngar Basin. The research results presented in this paper can provide guidance for evaluating CO2 storage potential in deep coal seams.



中文翻译:

次烟煤中不同压力和温度下 CO2 吸附能力的测量:对 CO2 地质封存的意义

CCUS(碳捕获、利用和储存)技术被认为是全球实现碳中和的底层方法。深层煤储层中的CO 2封存是 CCUS 的可行选择,其封存潜力可归因于煤的CO 2吸附能力。本文对南准噶尔盆地次烟煤(储层温度~25.9℃,压力~3.91 MPa)进行了一系列不同压力和温度下的CO 2吸附等温线实验。此外,利用超临界DR吸附模型表征了准噶尔盆地南部煤的高压CO 2吸附特性。最后,CO 2分析了原位储层温度和压力下次烟煤的储存能力。结果表明,在达到~34.55 cm 3 /g的渐近最大值之前,过剩吸附容量随着注入压力的增加而逐渐增加。超临界 DR 吸附模型适用于表征过量/绝对 CO 2吸附容量,如 > 0.99 的高相关系数所示。CO 2吸附量随温度降低而增加,表明温度对CO 2有负面影响地质封存。通过分析DR吸附拟合参数与储层温度的统计关系,建立了CO 2吸附容量演化模型,可进一步用于预测原位储层条件下CO 2封存潜力。CO 2吸附容量在达到临界 CO 2密度之前缓慢增加,随后在准噶尔盆地南部深度大于 ~ 800 m 处迅速减少。本文的研究结果可为评估深层煤层中CO 2封存潜力提供指导。

更新日期:2023-06-09
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