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Design and Analysis of Lead-Free Tin-Halide-Based All-Inorganic Perovskite Solar Cell for High Efficiency
Nano ( IF 1.2 ) Pub Date : 2023-06-09 , DOI: 10.1142/s1793292023500492
Hemant Kumar 1 , Piush Verma 1 , Balwinder Raj 2
Affiliation  

This research work presents a lead-free, environment-friendly, tin-halide-based perovskite solar cell (PSC). In our research, we employed Cs2SnI6 as an absorber layer, which is coupled with several different inorganic electron transport layers (ETLs) and hole transport layers (HTLs) for experimental purposes. These various permutations of the device structure are simulated and optimized in the SCAPS-1D simulator to achieve the highest possible efficiency. In our work, we suggested the architecture of ZnO/Cs2SnI6/Cu2O which is the most suitable for effective and long-lasting PSCs with exceptional device performance. In addition, we investigated and evaluated the impact of several parameters like HTLs, ETLs, absorber thicknesses, defect densities, operating temperature and series resistance over device performance. The proposed configuration displayed excellent power conversion efficiency (PCE) of 30.11% with 1.49V, 27.25 mA/cm2 and 73.66% of open-circuit voltage (VOC), short-circuit current (JSC) and fill factor (FF), respectively, and is pertinent for lead-less, tin-halide-based PSCs in the future.



中文翻译:

高效率无铅卤化锡基全无机钙钛矿太阳能电池的设计与分析

这项研究工作提出了一种无铅、环保的卤化锡基钙钛矿太阳能电池(PSC)。在我们的研究中,我们采用Cs 2 SnI 6作为吸收层,其与几种不同的无机电子传输层(ETL)和空穴传输层(HTL)耦合用于实验目的。器件结构的这些不同排列在 SCAPS-1D 模拟器中进行模拟和优化,以实现尽可能高的效率。在我们的工作中,我们提出了 ZnO/Cs 2 SnI 6 /Cu 2的结构O 最适合具有卓越器件性能的有效且持久的 PSC。此外,我们还研究并评估了 HTL、ETL、吸收体厚度、缺陷密度、工作温度和串联电阻等几个参数对器件性能的影响。所提出的配置显示出出色的功率转换效率 (PCE),为 30.11%,1.49V,27.25 mA/cm 2和开路电压的 73.66%(V奥克,短路电流(JSC和填充因子 (FF),分别与未来无铅卤化锡 PSC 相关。

更新日期:2023-06-09
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