This account describes the construction of supramolecular constructs based on our bis(porphyrin) cleft molecule. The bis(porphyrin) cleft molecule was originally synthesized as a tweezer-shaped host molecule for planar guest molecules. A detailed study on the bis(porphyrin) cleft molecule revealed that the bis(porphyrin) cleft molecule forms two kinds of supramolecular structures. One structure is a self-complementary dimer obtained through intermolecular hydrogen bonding, and the other structure is a host-guest complex, in which the electron-rich cleft cavity accommodates electron-deficient guests through donor-acceptor interactions. Through the two supramolecular structures, two distinct supramolecular polymers can be formed through self-complementary dimerization or donor-acceptor host-guest complexation. The supramolecular chain structures were modified by judiciously using two distinct supramolecular structures. In the main text, several results, including the binding capability of our bis(porphyrin) cleft molecule, the formation of supramolecular porphyrin complexes, and the supramolecular polymerization behaviors of the bis(porphyrin) cleft molecule, are reported. In conclusion, the future direction of the bis(porphyrin) cleft molecule is provided.

该描述描述了基于我们的双（卟啉）裂口分子的超分子结构的构建。双（卟啉）裂口分子最初是作为平面客体分子的镊子形主体分子合成的。对双(卟啉)裂隙分子的详细研究表明，双(卟啉)裂隙分子形成两种超分子结构。一种结构是通过分子间氢键形成的自互补二聚体，另一种结构是主客体复合物，其中富电子的裂隙腔通过供体-受体相互作用容纳缺电子的客体。通过两种超分子结构，可以通过自互补二聚或供体-受体主-客体络合形成两种不同的超分子聚合物。通过明智地使用两种不同的超分子结构来修饰超分子链结构。在正文中，报告了一些结果，包括双（卟啉）裂口分子的结合能力、超分子卟啉复合物的形成以及双（卟啉）裂口分子的超分子聚合行为。总之，提供了双(卟啉)裂口分子的未来发展方向。