Journal of Porphyrins and Phthalocyanines ( IF 1.5 ) Pub Date : 2023-06-19 , DOI: 10.1142/s1088424623500980 Hidemitsu Uno 1 , Shogo Hata 1 , Kohei Hashimoto 1 , Kota Muramatsu 1 , Hideyuki Nakano 1 , Takahiro Takiue 1 , Hiroki Uoyama 1 , Yuma Tanioka 1 , Shigeki Mori 2 , Tetsuo Okujima 1 , Masayoshi Takase 1
Two blueish materials were obtained in the acid-catalyzed condensation of 5-pentafluorophenyldipyrromethane-1,9-bis{(petafluorophenyl)-methanol} with 4,8-dihydro-4,8-ethanopyrrol[3,4-]isoindole followed by oxidation, although the yields were low. Their structures were unambiguously determined by the X-ray analysis. One was ethylene-connected bisdipyrromethene and another was bicyclo[2.2.2]octene-crosslinked dihydrohexaphyrin, which was gradually transformed to benzene-crosslinked hexaphyrin under air in solution via bicyclo[2.2.2]octadiene-crosslinked hexaphyrin. The benzene-crosslinked hexaphyrin was directly obtained in the similar acid-catalyzed condensation procedure of the dipyrromethane with 4,8-dihydropyrrol[3,4-]isoindole, although the yield was also low.
中文翻译:
苯交联六菲林:六菲林中的苯分子
5-五氟苯基二吡咯甲烷-1,9-双{(五氟苯基)-甲醇}与4,8-二氢-4,8-乙醇吡咯[3,4-]在酸催化下缩合得到两种蓝色物质。]异吲哚,然后氧化,尽管产率较低。通过 X 射线分析明确确定了它们的结构。一种是乙烯连接的双二吡咯亚甲基,另一种是双环[2.2.2]辛烯交联的二氢六菲林,在空气中在溶液中通过双环[2.2.2]辛二烯交联的六菲林逐渐转化为苯交联的六菲林。通过类似的二吡咯甲烷与4,8-二氢吡咯[3,4-]的酸催化缩合过程直接获得苯交联的六菲啉。]异吲哚,但产率也较低。