Transactions of the Indian Ceramic Society ( IF 1.2 ) Pub Date : 2023-06-27 , DOI: 10.1080/0371750x.2023.2205600 Sukru Cavdar 1 , Yesim Demirolmez 1 , Neslihan Turan 1 , Haluk Koralay 1 , Nihat Tugluoglu 2
In this article, structural, morphological and electrical properties of ZnCo2O4 ceramics sample were studied. ZnCo2O4 nanoparticles were synthesized using sol-gel method. Structural and morphological properties of the sample were analyzed using X-ray diffraction and scanning electron microscope. Conductance, capacitance and impedance spectroscopy characterization of ZnCo2O4 ceramics sample were analyzed in 3 kHz-1.5 MHz frequency range and 300-500 K temperature range. Nyquist diagrams of impedance and the equivalent circuit were studied for ZnCo2O4 ceramics in the temperature range of 300-500 K. Cole-Cole curves of the impedance data were found to show a semicircular arc in both low and high temperature areas, which is expressed by the equivalent electrical circuit Rs(RgCg)(RgbQCgb). Relaxation behavior was identified to be of non-Debye type. The Cole-Cole curve showed the negative temperature coefficient of resistance type behavior. Values of the activation energy corresponding to relaxation processes were found as 0.054 eV below 360 K and 0.561 eV above 360 K.
中文翻译:
溶胶-凝胶法获得的ZnCo2O4陶瓷的阻抗谱表征
本文对ZnCo 2 O 4陶瓷样品的结构、形貌和电学性能进行了研究。采用溶胶-凝胶法合成了ZnCo 2 O 4纳米颗粒。使用 X 射线衍射和扫描电子显微镜分析样品的结构和形态特性。在3 kHz-1.5 MHz频率范围和300-500 K温度范围内分析了ZnCo 2 O 4陶瓷样品的电导、电容和阻抗谱表征。研究了ZnCo 2 O 4的阻抗奈奎斯特图和等效电路陶瓷在300-500 K温度范围内的阻抗数据的Cole-Cole曲线在低温区和高温区均呈现半圆弧,用等效电路R s ( R g C g )表示(R国标QC国标)。放松行为被确定为非德拜类型。科尔-科尔曲线显示电阻型行为的负温度系数。弛豫过程对应的活化能值在 360 K 以下为 0.054 eV,在 360 K 以上为 0.561 eV。