Functional Materials Letters ( IF 1.3 ) Pub Date : 2023-07-17 , DOI: 10.1142/s1793604723400222 Huiya Li 1 , Yaoyao Li 1 , Xiaomeng Wang 1 , Zicheng Zhang 1 , Dejia Liu 1 , Haiyun Ma 2 , Hongqiang Qu 2 , Jianzhong Xu 2 , Yuanyuan Han 3 , Liyong Wang 1
Green-emitting Mn-doped zinc silicate nanophosphor was synthesized by solvothermal method with the assistance of polyvinyl alcohol (PVA). The structure, morphology and optical properties of phosphors were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Scanning electron microscope (SEM), Fourier transform infrared spectrometer (FT-IR) and Photoluminescence Spectroscopy (PL). Also, the application of Mn-doped zinc silicate phosphor in electronic devices was studied. Furthermore, Zn2SiO4: Mn phosphor was used to be a fluorescent sensor for the first time to detect inorganic ions and small molecules. The results indicated that pure -Zn2SiO4 phase nanoparticles with spherical morphology were obtained. The results also showed that the phosphor has excellent selectivity and sensitivity for detecting Cr ions, Cr2O7 ions and 4-nitrophenol (4-NP) with low detection limits (Cr ions: 1.34 M, Cr2O7 ions: 5.86 M, 4-NP: 2.38 M). Thus, Mn-doped zinc silicate manganese phosphor has potential applications in light-emitting diodes (LEDs) and fluorescent sensors.
中文翻译:
PVA 辅助合成 Zn2SiO4:Mn2+ 纳米粒子:增强的发光性能和应用
绿光锰以聚乙烯醇(PVA)为辅助剂,采用溶剂热法合成了掺杂硅酸锌纳米荧光粉。采用X射线衍射(XRD)、X射线光电子能谱(XPS)、扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)和光致发光光谱(PL)等手段对荧光粉的结构、形貌和光学性能进行了表征。 )。另外,锰的应用研究了电子器件中的掺杂硅酸锌荧光粉。此外,Zn 2 SiO 4 :Mn首次使用荧光粉作为荧光传感器来检测无机离子和小分子。结果表明,纯获得了具有球形形貌的-Zn 2 SiO 4相纳米颗粒。结果还表明,该荧光粉对Cr检测具有优异的选择性和灵敏度。离子,Cr 2 O 7离子和 4-硝基苯酚 (4-NP) 的检测限较低(Cr离子:1.34M、Cr 2 O 7离子:5.86M,4-NP:2.38米)。因此,锰掺杂硅酸锌锰荧光粉在发光二极管(LED)和荧光传感器中具有潜在的应用。