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Comparative study of Fe2B3O7 and Mn4(B6O13(OH)): a new structure linking melilite and johachidolite
Zeitschrift für Naturforschung B ( IF 0.8 ) Pub Date : 2023-08-18 , DOI: 10.1515/znb-2023-0047 Leonard C. Pasqualini 1 , Hubert Huppertz 1
Zeitschrift für Naturforschung B ( IF 0.8 ) Pub Date : 2023-08-18 , DOI: 10.1515/znb-2023-0047 Leonard C. Pasqualini 1 , Hubert Huppertz 1
Affiliation
The two compounds Fe2 B3 O7 (a = 663.61(4), c = 438.39(3) pm, space group: P 4 ‾ $\overline{4}$ 21 m ) and Mn4 (B6 O13 (OH)) (a = 445.14(1), b = 683.56(2), c = 1330.34(3) pm, β = 90.42(1)°, space group: P 21 /c ) were synthesized under high-pressure/high-temperature conditions of 9 GPa and 800 °C. Their crystal structures have been determined via single-crystal X-ray diffraction and the occurring side-phases have been identified. Fe2 B3 O7 crystallizes in the melilite structure type, whereas the novel structure of Mn4 (B6 O13 (OH)) can be derived from the structures of the minerals melilite or johachidolite.
中文翻译:
Fe2B3O7 和 Mn4(B6O13(OH)) 的比较研究:连接黄长石和六角石的新结构
两种化合物Fe2 乙3 氧7 (A = 663.61(4),C = 438.39(3) pm,空间组:磷 4 ‾ $\上划线{4}$ 21 米 )和锰4 (乙6 氧13 (哦)) (A = 445.14(1),乙 = 683.56(2),C = 1330.34(3) 下午,β = 90.42(1)°,空间群:磷 21 /C )在9 GPa和800 °C的高压/高温条件下合成。它们的晶体结构已确定通过 单晶 X 射线衍射和发生的副相已被识别。铁2 乙3 氧7 以黄长石结构类型结晶,而 Mn 的新颖结构4 (乙6 氧13 (OH)) 可以源自矿物黄长石或角石石的结构。
更新日期:2023-08-18
中文翻译:
Fe2B3O7 和 Mn4(B6O13(OH)) 的比较研究:连接黄长石和六角石的新结构
两种化合物Fe