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Estimation of the Shape Factor of Aggregates in Self-Associating Systems Based on Metallosurfactants
Colloid Journal ( IF 1.1 ) Pub Date : 2023-08-17 , DOI: 10.1134/s1061933x23600252
E. P. Zhil’tsova , D. R. Islamov , L. Ya. Zakharova

Abstract—

A mathematical evaluation of the shape factor of aggregates formed by amphiphilic compounds in an aqueous medium has been carried out on the basis of dynamic light scattering data for self-associating systems based on metallocomplexes of alkylated derivatives of 1,4-diazabicyclo[2.2.2]octane with Ag(I) and Gd(III) nitrates, a ligand, and a ligand–inorganic salt mixture. Micellar and vesicular approximations have been used. A relationship between the shape factor and the parameters of the water pool of an aggregate has been shown for vesicular systems.



中文翻译:

基于金属表面活性剂的自缔合体系中聚集体形状因子的估计

摘要-

基于 1,4-二氮杂双环烷基化衍生物金属络合物的自缔合体系的动态光散射数据,对水性介质中两亲性化合物形成的聚集体的形状因子进行了数学评估。 ]辛烷与硝酸银(I)和硝酸钆(III)、配体以及配体-无机盐混合物。已使用胶束和囊泡近似。对于囊泡系统,形状因子与骨料水池参数之间的关系已被证明。

更新日期:2023-08-19
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