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Hydrogeochemical signatures origin of a karst geothermal reservoir–the Sinian Dengying Formation in northern Guizhou, China
Geosciences Journal ( IF 1.2 ) Pub Date : 2023-09-16 , DOI: 10.1007/s12303-023-0030-9
Pu Liu , Zhengshan Chen , Ganlu Wang , Tie Mao , Chao Li , Yanan Zhou , Hong Xie , Tong Xiang

The karst geothermal reservoir, Sinian Dengying Formation was investigated from the hydrogeochemical perspective. Integrated techniques including XRD + SEM, isotopes, saturation index and PHREEQC modeling were applied. With 37.3–72 ?, the targeted waters indicate low-mediate temperature geothermal reservoir. The CO2 concentration in the geothermal waters varies from 1.2 mg/L to 52.42 mg/L, and the log(PCO2) value ranges from −2.53 to −1.29, indicating an open carbonate system. A further D-18O stable isotope analysis addresses the geothermal waters are replenished by meteoric water from +815.52 m to +1427.78 m. Strong water-rock interactions are indicated by apparent 18O shift. The dominating hydrochemical type is SO4·HCO3-Ca·Mg with some Cl-Na. The CO2-TDS-SI-Carbonates comprehensive analysis illustrate the origin of Ca2+, Mg2+, and HCO3, mainly from dolomite. The correlation of 18O-SO42-SI_Gypsum gives sound evidence for the processes of gypsum dissolution. Three inverse models were established and the results showed, that geothermal waters are controlled by two major factors: 1) the adjacent location to salt basin geological profiles with halite dissolution; and 2) the clay minerals such as Na-montmorillonite causing cation exchanges between Na+ and Ca2+ in the geothermal waters, resulting in excess of Na in relation to Cl concentrations.



中文翻译:

贵州北部震旦系灯影组岩溶地热储层水文地球化学特征成因

从水文地球化学角度对震旦系灯影组岩溶地热储层进行了研究。应用了 XRD + SEM、同位素、饱和指数和 PHREEQC 建模等综合技术。目标水域温度为37.3~72℃,属于中低温地热储层。地热水中CO 2浓度变化范围为1.2 mg/L至52.42 mg/L,log(P CO2 )值变化范围为-2.53至-1.29,表明存在开放碳酸盐系统。进一步的 D- 18 O 稳定同位素分析表明,+815.52 m 至 +1427.78 m 范围内的地热水由大气水补充。明显的18 O 位移表明强烈的水-岩石相互作用。主要的水化学类型是 SO 4·HCO 3 -Ca·Mg 和一些 Cl-Na。CO 2 -TDS-SI-碳酸盐综合分析表明Ca 2+、Mg 2+和HCO 3 -的来源主要来自白云石。18 O-SO 4 2 -SI_Gypsum的相关性为石膏溶解过程提供了可靠的证据。建立了三个反演模型,结果表明,地热水受两个主要因素控制:1)邻近盐盆地质剖面,有岩盐溶蚀;2)粘土矿物,例如Na-蒙脱石,引起Na +和Ca 2+之间的阳离子交换在地热水中,导致 Na 相对于 Cl 浓度过量。

更新日期:2023-09-16
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