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Hydraulic conductivity and multi-scale pore structure of polymer-enhanced geosynthetic clay liners permeated with bauxite liquors
Geotextiles and Geomembranes ( IF 5.2 ) Pub Date : 2023-09-28 , DOI: 10.1016/j.geotexmem.2023.09.004
Xing Chen , Yu Tan , Jiannan Chen , Daoping Peng , Tao Huang , Chunxiao Meng

A study was conducted to investigate the multi-scale pore structure-based mechanism controlling the hydraulic conductivity of polymer-enhanced geosynthetic clay liners (GCLs) prepared by the wet-mixed method to bauxite liquors (BLS and BLA). The multi-scale pore structures were evaluated using MIP and N2GA tests quantitatively. Conventional GCL permeated with BLS had a larger flow path volume than with DI water (0.194 > 0.119 cm³/g), attributed to the bentonite swelling inhibition and the montmorillonite dissolution, leading to the higher hydraulic conductivity (3.0 × 10−7 > 2.7 × 10−11 m/s). Polymer-enhanced GCLs developed more micropores and had a smaller quantity proportion and volume of flow paths since polymer formed more micropores to clog pores, contributing to a lower hydraulic conductivity than conventional GCL to BLS. The hydraulic conductivity of polymer-enhanced GCL to BLS (ionic strength: 622.5 mM) was higher than that to BLA (156.9 mM) (2.6 × 10−9 > 6.0 × 10−12 m/s), given that the coiled or contracted polymer conformation left a smaller quantity proportion (5.54% < 6.71%) and volume (0.0002 cm3/g < 0.0035 cm3/g) of micropores.



中文翻译:

铝土矿液渗透聚合物增强土工合成粘土衬垫的导水率和多尺度孔隙结构

进行了一项研究,以研究基于多尺度孔隙结构的机制,控制聚合物增强土工合成粘土衬垫(GCL)的导水率,该衬垫是通过湿法混合法与铝土矿溶液(BLS 和 BLA)制备的。使用MIP和N2 GA测试定量评估多尺度孔隙结构。渗透BLS的传统GCL比去离子水具有更大的流路体积(0.194 > 0.119 cm3/g),这归因于膨润土膨胀抑制和蒙脱石溶解,导致更高的导水率(3.0 × 10 -7 > 2.7 × 10-11  m/s)。聚合物增强的 GCL 形成更多的微孔,并且由于聚合物形成更多的微孔而堵塞孔隙,因此具有更小的数量比例和流道体积,从而导致比传统 GCL 到 BLS 更低的导水率。 考虑到卷曲或收缩,聚合物增强 GCL 对 BLS(离子强度:622.5 mM)的水力传导率高于对 BLA(156.9 mM)的水力传导率(2.6 × 10-9 > 6.0 × 10-12聚合物构象留下了较小的微孔数量比例(5.54% < 6.71%)和体积(0.0002 cm3/g < 0.0035 cm3/g)。

更新日期:2023-09-28
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