In this paper, 1-naphthoic acid, 2,2-dipyridyl (Bipy) and cupric nitrate are used to synthesize a novel complex by hydrothermal method. The complex is characterized by means of IR and X-ray diffraction. The complex is applied in the hydroxylation of phenol and the degradation of Congo Red as catalysts. The influence of dosage of catalyst, reaction time, temperature, etc. is studied in both hydroxylation of phenol and the degradation of Congo Red. The best results of the phenol hydroxylation reaction are obtained by reacting 0.2 g phenol with 0.30 mL hydrogen peroxide (30%) at 80 ℃ for 180 min under the catalysis of 8 mg complex. The yield of benzenediol is 81.45%. The optimum degradation of Congo Red reaction is achieved by mixing 0.75 mg Congo Red with 4 mg complex, 0.30 mL hydrogen peroxide and reacting at 45 ℃, for 30 min.

中文翻译：

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1-萘甲酸盐-铜-联吡啶配合物的合成及催化性能

本文采用1-萘酸、2,2-联吡啶(Bipy)和硝酸铜通过水热法合成了一种新型配合物。该配合物通过红外和X射线衍射进行表征。该配合物作为催化剂应用于苯酚羟基化和刚果红降解。研究了催化剂用量、反应时间、温度等对苯酚羟基化和刚果红降解的影响。苯酚羟基化反应的最佳结果是在8 mg络合物的催化下，0.2 g苯酚与0.30 mL过氧化氢(30%)在80 ℃下反应180 min。苯二酚的收率为81.45%。刚果红的最佳降解反应为将 0.75 mg 刚果红与 4 mg 复合物、0.30 mL 过氧化氢混合并在 45 ℃ 下反应 30 min。