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Physical properties and crystal structure of near end-member oxy-dravite from the Beluga occurrence, Nunavut territory, Canada
Mineralogical Magazine ( IF 2.7 ) Pub Date : 2023-08-07 , DOI: 10.1180/mgm.2023.59
Lenka Skřápková , Jan Cempírek , Philippe M. Belley , Lee A. Groat , Radek Škoda

Oxy-dravite, ideally Na(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3(O), was found in a composition near its ideal end-member at the Beluga occurrence, Nunavut territory, Canada. It occurs in retrograde albite–muscovite–corundum–calcite domains in a calc-silicate rock. This uncommon oxy-dravite occurs as dark brown, equant to short-prismatic, idiomorphic crystals with vitreous lustre and up to ca. 4 × 3 cm in size. The oxy-dravite is optically uniaxial (–), with ω = 1.6453(5) and ɛ = 1.6074(18); its calculated density is 3.069 g.cm–3 with a compatibility index of 0.016. The Beluga oxy-dravite has trigonal symmetry, space group R3m with a = 15.9121(2) Å, c = 7.1788(10) Å, V = 1574.12(5) Å3 and Z = 3. The crystal structure was refined to R1 = 1.45 using 1613 unique reflections. The empirical crystal-chemical formula is X(Na0.88Ca0.080.03K0.01)Y(Al1.49Mg1.31Fe0.15Ti0.04Zn0.01)Z(Al5.42Mg0.58)T(Si5.84Al0.16O18)B(BO3)3V(OH2.95O0.05)W(O0.84OH0.01F0.15).

Oxy-dravite in nature commonly occurs in a solid solution with foitite, schorl and oxy-schorl. At the Beluga occurrence, its minor contents of Al, vacancy [□], and Ca are most likely compensated by (□Al)(NaR2+)–1 and (CaMg)(NaAl)–1 exchanges of the oxy-magnesio-foitite and magnesio-lucchesiite components. The Beluga occurrence of oxy-dravite is characterised by an Mg-rich environment related to a metamorphic overprint of the original sedimentary sequence. This sequence of marine dolomitic argillaceous marl was influenced by (B,Cl)-rich fluids, probably proximally-derived from mineral breakdown reactions in the calc-silicate during the retrograde stage of metamorphism. The locality is a rare example of a tourmaline + corundum assemblage.



中文翻译:

加拿大努纳武特地区白鲸矿区近端元氧镁铁矿的物理性质和晶体结构

氧镁镁石,理想情况下为 Na(Al 2 Mg)(Al 5 Mg)(Si 6 O 18 )(BO 3 ) 3 (OH) 3 (O),在 Beluga 矿点发现其成分接近其理想端元,努纳武特地区,加拿大。它发生在钙硅酸盐岩石的逆行钠长石-白云母-刚玉-方解石域中。这种不常见的氧镁铁矿呈深棕色,相当于具有玻璃光泽的短棱柱状异质晶体,尺寸可达约 100 微米。尺寸为 4 × 3 厘米。氧镁镁石具有光学单轴性 (–),ω = 1.6453(5) 和 ɛ = 1.6074(18);其计算密度为3.069 g.cm –3,相容性指数为0.016。Beluga 氧化钠镁石具有三角对称性,空间群R 3 m a = 15.9121(2) Å,c = 7.1788(10) Å,V = 1574.12(5) Å 3Z = 3。晶体结构精修为R 1 = 1.45,使用 1613 个独特的反射。经验晶体化学式为X (Na 0.88 Ca 0.080.03 K 0.01 ) Y (Al 1.49 Mg 1.31 Fe 0.15 Ti 0.04 Zn 0.01 ) Z (Al 5.42 Mg 0.58 ) T (Si 5.84 Al 0.16 O 18 ) B (BO 3 ) 3V (OH 2.95 O 0.05 ) W ( O 0.84 OH 0.01 F 0.15 )。

自然界中的氧化镁镁石通常以与镁铁矿、氧化镁镁石和氧化氧化镁镁石的固溶体形式存在。在 Beluga 矿点,其少量的 Al、空位 [□] 和 Ca 最有可能通过 (□Al)(NaR 2+ ) –1和 (CaMg)(NaAl) –1氧镁交换来补偿。镁铁矿和镁镁铁矿成分。白鲸的氧化镁镁矿产状的特点是富镁环境,与原始沉积序列的变质叠印有关。这一序列的海洋白云质泥质泥灰岩受到富含 (B,Cl) 流体的影响,这些流体可能近端源自变质作用逆行阶段硅酸钙中的矿物分解反应。该地区是电气石+刚玉组合的罕见例子。

更新日期:2023-08-07
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