We first describe a photoinduced decatungstate-catalyzed direct coupling of cycloalkanes and cyclic aldimines. The desired products were generated in moderate to good yields with wide substrate scope under mild reaction conditions. The mechanistic study revealed a radical process. In addition, the usefulness of the reaction in organic synthesis was proved by the scale-up synthesis as well as the late-stage modification of drug-like molecules.

中文翻译：

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光诱导十钨酸盐催化环烷烃与环状醛亚胺的直接偶联

我们首先描述了环烷烃和环状醛亚胺的光诱导十钨酸盐催化直接偶联。在温和的反应条件下，以中等至良好的产率生成了所需的产物，底物范围广泛。机理研究揭示了一个根本性的过程。此外，该反应在有机合成中的实用性通过类药物分子的放大合成和后期修饰得到了证明。