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Some thermodynamic properties of SF6 on the binodal in the vicinity of the critical point
Thermophysics and Aeromechanics ( IF 0.5 ) Pub Date : 2023-10-23 , DOI: 10.1134/s0869864323030149
E. E. Ustyuzhanin , V. F. Ochkov , V. A. Rykov , S. V. Rykov , I. V. Kudryavtseva

The presented paper considers a number of problems, with the first of them concerning the analysis of experimental (ρl, ρg, T)-data of SF6 at relative temperatures (1.5·10−8 < τ < 0.3). The second task is to develop combined models (ρl (D, C, τ), ρg (D, C, τ), …) that agree with a number of boundary conditions, including the requirements of the scale theory of critical phenomena. The third task deals with the calculation of (D, C)-parameters included in the combined models; at this stage, a basic array of (ρl, ρg, T)-data is formed. It contains: a) experimental results obtained in the laboratory of Prof. Funke (Germany) and b) (ρl, ρg, T)-data obtained by recalculating some values in the laboratory of Prof. Garrabos (France). The models ρl (D, C, τ) and ρg (D, C, τ) serve as the basis for computing some thermodynamic functions of SF6 in the critical region; among them there are complexes, which consist of several properties (the average diameter of a binodal, the order parameter etc.).



中文翻译:

临界点附近双节上SF6的一些热力学性质

本文考虑了许多问题,其中第一个问题涉及相对温度 (1.5·10 -8 < τ < 0.3) 下SF 6的实验 ( ρ l , ρ g , T ) 数据分析。第二个任务是开发符合许多边界条件的组合模型 ( ρ l ( D , C , τ ), ρ g ( D , C , τ ), …),包括临界现象尺度理论的要求。第三个任务涉及组合模型中包含的( D , C ) 参数的计算;在此阶段,形成了( ρ l , ρ g , T )-数据的基本数组。它包含:a)在Funke教授(德国)实验室获得的实验结果和b)(ρl ρg T)-在Garrabos教授(法国)实验室重新计算一些值获得的数据。模型ρ l ( D , C , τ ) 和ρ g ( D , C , τ ) 是计算SF 6在临界区的一些热力学函数的基础;其中有复合体,由多个属性组成(双节的平均直径、阶次参数等)。

更新日期:2023-10-23
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