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Aloe vera mucilage as an eco-friendly corrosion inhibitor for bronze in chloride media: Combining experimental and theoretical researches
Journal of King Saud University-Science ( IF 3.8 ) Pub Date : 2023-11-01 , DOI: 10.1016/j.jksus.2023.102986
Bouchra Benzidia , Mohammed Barbouchi , Malak Rehioui , Hind Hammouch , Hamid Erramli , Najat Hajjaji

Aloe vera (L.) Burm.F. (= Aloe barbadensis Mill.), a widely recognized medicinal plant, holds a prominent position due to its potent cosmetic and medicinal attributes. The objective of this work is to develop a new eco-friendly corrosion inhibitor for bronze B66 that is non-toxic, simple to apply, cost-effective, stable, and reversible. To achieve this goal, we initially devised an improved and cost-efficient method for extracting Aloe vera mucilage (AVM). Then we tested as corrosion inhibitor for bronze B66 in 3% NaCl using gravimetric measurements, electrochemical methods and Scanning Electron Microscopy (SEM) coupled with Energy Dispersive X-Ray analysis (EDX). The electrochemical assessments validated the findings from the gravimetric analysis and demonstrated that our inhibitor significantly modifies the electrochemical process mechanism at the B66/3% NaCl interface. The corrosion rate of bronze decreases with the inhibitor's presence, and its inhibitory effectiveness amplifies with higher concentrations, reaching an efficiency of 86% at 750 ppm. The mechanism of metallic copper and corrosion Acemannan inhibitor was explored through DFT studies and molecular dynamics simulation.



中文翻译:

芦荟粘液作为氯化物介质中青铜的环保缓蚀剂:实验与理论研究相结合

芦荟 (L.) Burm.F. (= Aloe barbadensis Mill .),一种广泛认可的药用植物,由于其有效的美容和药用特性而占据显着地位。这项工作的目的是开发一种新型环保型青铜 B66 缓蚀剂,该缓蚀剂无毒、使用简单、经济高效、稳定且可逆。为了实现这一目标,我们最初设计了一种改进且经济高效的方法来提取芦荟粘液(AVM)。然后,我们使用重量测量、电化学方法、扫描电子显微镜 (SEM) 以及能量色散 X 射线分析 (EDX) 来测试青铜 B66 在 3% NaCl 中的缓蚀剂。电化学评估验证了重量分析的结果,并证明我们的抑制剂显着改变了 B66/3% NaCl 界面的电化学过程机制。青铜的腐蚀速率随着抑制剂的存在而降低,并且其抑制效果随着浓度的增加而增强,在 750 ppm 时达到 86% 的效率。通过DFT研究和分子动力学模拟,探讨了金属铜和乙酰化甘露聚糖缓蚀剂的作用机理。

更新日期:2023-11-02
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