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Synergistic effect of CO2-mineralized steel slag and carbonation curing on cement paste
Cement and Concrete Composites ( IF 10.5 ) Pub Date : 2023-11-11 , DOI: 10.1016/j.cemconcomp.2023.105357
Linshan Li , Tiefeng Chen , Xiaojian Gao

Cement-based materials have favorable capacity of solid waste and CO2 disposal. In this study, a synergistic CO2 treatment, including CO2 mineralization of steel slag admixture and carbonation curing of cement paste, was proposed. The influence of synergistic CO2 treatment on pozzolanic activity of steel slag, CO2 sequestration, and compressive strength of specimens were investigated. Results show that synergistic CO2 treatment cannot significantly increase the compressive strength but can improve the CO2 sequestration efficiently (up to 10.76 %), while a single CO2 treatment could only improve CO2 sequestration by 6.75 %. MIP, 29Si NMR, XRD-rietveld, and Raman spectroscopy were used to determine the effect of synergistc CO2 treatment on microstructure and mineral composition of samples. A barrier layer generated on the surface of steel slag particle was observed in SEM images. This barrier layer composed of carbonates reduces the early activity of CO2 mineralized steel slag.



中文翻译:

CO2矿化钢渣与碳化养护对水泥净浆的协同效应

水泥基材料具有良好的固体废物和CO 2处理能力。本研究提出了一种协同CO 2处理方法,包括钢渣掺合料的CO 2矿化和水泥浆的碳化固化。研究了协同CO 2处理对钢渣火山灰活性、CO 2封存和试样抗压强度的影响。结果表明,协同CO 2处理不能显着提高抗压强度,但可以有效提高CO 2封存量(高达10.76 %),而单一CO 2处理只能提高CO 2封存量6.75 %。MIP、29 Si NMR、XRD-rietveld 和拉曼光谱用于确定协同CO 2处理对样品微观结构和矿物组成的影响。在SEM图像中观察到钢渣颗粒表面生成了阻挡层。该由碳酸盐组成的阻挡层降低了CO 2矿化钢渣的早期活性。

更新日期:2023-11-11
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