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Study on the explosion characteristics and flame propagation of hydrogen-methane-air mixtures in a closed vessel
Journal of Loss Prevention in the Process Industries ( IF 3.5 ) Pub Date : 2023-11-22 , DOI: 10.1016/j.jlp.2023.105224
Lu Liu , Zhenmin Luo , Bin Su , Fangzhi Song , Pengzhi Wu , Tao Wang , Jun Deng

In this study, the examination of the explosion pressure and flame propagation characteristics were investigated for premixed CH4–H2-air mixtures, with varying equivalence ratios (φ = 0.8–1.5) and methane volume ratios (R = 0–100%). This investigation was conducted employing a 20 L explosion vessel and a high-speed ripple shadow meter, while maintaining ambient temperature and pressure. The most critical primitive reactions effecting the formation and consumption of OH* were obtained by normalisation through rate analysis. The result found that as the R increased at the same φ, the premixed system exhibited a gradually decreased in the Pmax, (dP/dt)max, and KG. The increase in the R caused the flame structure to stabilise, extending the flame front distance and the time to reach the wall. The reaction process was divided into three phases based on the R: 0 < R<40% (dominated by hydrogen combustion), 40% < R<80% (dominated by methane and hydrogen co-combustion), and 80% < R<100% (dominated by methane combustion). The analysis of OH* production rate showed that R84 and R38 were the most dominant reactions promoting the OH* production and consumption, respectively. As R was increased, both the production and consumption rates of OH* decreased resulting in a weakening of the explosive reaction's intensity.



中文翻译:

密闭容器内氢气-甲烷-空气混合物爆炸特性及火焰传播研究

在本研究中,研究了具有不同当量比 (φ = 0.8–1.5) 和甲烷体积比 (R = 0–100%) 的预混合 CH 4 –H 2 -空气混合物的爆炸压力和火焰传播特性。 。这项研究是使用 20 L 爆炸容器和高速波纹阴影仪进行的,同时保持环境温度和压力。通过速率分析进行归一化,获得了影响 OH* 形成和消耗的最关键的原始反应。结果发现,在相同的φ下,随着R的增加,预混体系的P max、(dP/dt) maxK G逐渐降低。R的增加导致火焰结构稳定,延长了火焰前锋距离和到达壁面的时间。根据R将反应过程分为三个阶段:0<R<40%(以氢气燃烧为主)、40%<R<80%(以甲烷和氢气共燃为主)、80%<R< 100%(主要是甲烷燃烧)。OH*产率分析表明,R84和R38分别是促进OH*产生和消耗的最主要反应。随着R的增加,OH*的产生和消耗速率均下降,导致爆炸反应强度减弱。

更新日期:2023-11-26
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