Based on the organocatalytic reaction of enamine azide addition of 2,4,6-triazido-1,3,5-triazine to acetylacetone acetoacetic ester, we synthesized a series of previously unknown mono-, di-, and tri(1,2,3-triazolyl)-substituted-1,3,5-triazines that additionally carried carbonyl, ester, and azide groups. The structure of the obtained compounds was proved by NMR (¹H, ¹³C) and IR spectroscopy, and the composition was confirmed by elemental analysis. With the aid of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) coupled to mass spectrometry (TG-MS), we obtained data on the thermal behavior and decomposition mechanism for these compounds. We demonstrated that di(1,2,3-triazolyl)-substituted 1,3,5-triazines have an increased thermal stability and have higher values of decomposition onset temperature (220–250 °C) in comparison with tri(1,2,3-triazolyl)-substituted 1,3,5-triazines (180 °C and 160 °C, respectively).

基于2,4,6-三叠氮基-1,3,5-三嗪与叠氮烯胺加成到乙酰丙酮乙酰乙酸酯的有机催化反应，我们合成了一系列以前未知的单、二和三(1,2, 3-三唑基)-取代的-1,3,5-三嗪还带有羰基、酯和叠氮基团。^{通过NMR( 1} H, ¹³ C)和IR光谱证实了所得化合物的结构，并通过元素分析确认了组成。借助差示扫描量热法 (DSC) 和热重分析 (TGA) 与质谱 (TG-MS) 相结合，我们获得了这些化合物的热行为和分解机制的数据。我们证明，与三(1,2)取代的1,3,5-三嗪相比，二(1,2,3-三唑基)取代的1,3,5-三嗪具有更高的热稳定性，并且具有更高的分解起始温度(220–250 °C) ,3-三唑基）取代的 1,3,5-三嗪（分别为 180 °C 和 160 °C）。