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Smelting of Fe–Si–Mn–Al Complex Alloy Using High-Ash Coal
Metallurgist ( IF 0.9 ) Pub Date : 2023-12-21 , DOI: 10.1007/s11015-023-01609-x
A. Nurumgaliyev , O. Zayakin , T. Zhuniskaliyev , B. Kelamanov , Y. Mukhambetgaliyev

Results of studies for preparing complex Fe–Si–Mn–Al master alloy are presented. High-silicon lean manganese ores of the West Kamys ore deposit (18–30% Mn and 35–45% SiO2) and high-ash coal of the Saryadyr deposit (Kazakhstan) with an ash content of 45–55% are used as charge materials. Technological studies are conducted in an ore-thermal electric furnace with a capacity of 250 kVA. An experimental batch of master alloy with an average chemical composition is obtained, %: Mn — 20; Si — 42; Al — 16; P — 0.03; Fe balance. Dependences of aluminum, silicon and manganese content in final alloy on ratios Mnox + Feox + SiO2 + Al2O3)/Cso and Mnox/(Mnox + Feox + SiO2 + Al2O3) in an initial charge are revealed. The fundamental possibility and expediency of obtaining an aluminum silicon manganese master alloy of a new composition by a slag-free method with integrated use of all useful components of lean manganese ore and high-ash coal is demonstrated. An X-ray diffraction pattern of prototypes indicates that alloy phase composition is presented in the form of intermetallics — MnSi, Mn15Si26, Al2Fe3Si4, Al5Fe2, FeSi, and structurally free silicon. The resulting master alloys of selected composition are not subject to self-dispersal reactions.



中文翻译:

高灰分煤冶炼铁硅锰铝复合合金

介绍了制备复杂 Fe-Si-Mn-Al 中间合金的研究结果。使用西卡梅斯矿床的高硅贫锰矿石(18-30% Mn 和 35-45% SiO 2 )和萨里亚德尔矿床(哈萨克斯坦)的灰分含量为 45-55% 的高灰分煤作为原料。充电材料。技术研究是在容量为250 kVA的矿热电炉上进行的。得到实验批次中间合金的平均化学成分,%:Mn—20;硅——42;阿尔——16;P——0.03;铁平衡。最终合金中铝、硅和锰含量对比率 Mn ox + Fe ox + SiO 2 + Al 2 O 3 )/C so和 Mn ox /(Mn ox + Fe ox + SiO 2 + Al 2 O 3 )的依赖性初步指控被揭露。论证了综合利用贫锰矿和高灰分煤各有用成分,采用无渣法获得新成分铝硅锰中间合金的根本可能性和便利性。原型的 X 射线衍射图表明,合金相成分以金属间化合物的形式存在 - MnSi、Mn 15 Si 26、Al 2 Fe 3 Si 4、Al 5 Fe 2、FeSi 和结构游离硅。所得的选定成分的母合金不会发生自分散反应。

更新日期:2023-12-22
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