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Influence of In2O3 on Optical, EPR, and Structural Properties of Barium Borate Glasses Containing Cu2+ Spin Probe
Brazilian Journal of Physics ( IF 1.6 ) Pub Date : 2024-01-08 , DOI: 10.1007/s13538-023-01413-7
Bodige Narsimha , K. Chandra Sekhar , Md. Shareefuddin , M. Narasimha Chary , Gokarakonda Ramadevudu

To evaluate the effect of In2O3 on (30-x) BaO-69B2O3-xIn2O3-1CuO (x = 0.5, 1.0, 1.5, 2.0 and 2.5 mol%) glasses are described for their spectroscopic properties as well as physical and optical qualities. Bragg’s peak-free X-ray diffractograms confirmed the samples’ non-crystalline character. The increase of In2O3mole percent in the glasses has caused non-linear fluctuations in the physical parameters such as density and molar volume. Urbach energy measurements and optical band gaps have shown modest inflections with In2O3 composition. The 2B1g → 2B2g transition is responsible for the broad distinctive absorption band seen in optical absorption spectra caused by the Cu2+ spin probe. The spin-Hamiltonian parameters’ non-linear variation with indium oxide content suggests that the ligand field strength surrounding Cu2+ ions in glass samples has changed. Bonding parameter values are determined using EPR and optical absorption spectrum data, and it is discovered that they are ionic in nature. According to FTIR tests, when the amount of indium oxide in the glass grew, a small percentage of BO3 units were converted into BO4 units. Indium oxide in these glasses appears to generate notable modifications in the electrical conduction, transparency, and semiconducting behavior, according to the behavior of their optical, physical, and spectroscopic qualities.



中文翻译:

In2O3 对含 Cu2+ 自旋探针的硼酸钡玻璃的光学、EPR 和结构性能的影响

为了评估 In 2 O 3对 (30-x) BaO-69B 2 O 3 -xIn 2 O 3 -1CuO ( x  = 0.5, 1.0, 1.5, 2.0 和 2.5 mol%) 玻璃的光谱特性的影响以及物理和光学品质。布拉格的无峰 X 射线衍射图证实了样品的非结晶特性。玻璃中In 2 O 3摩尔百分比的增加导致物理参数如密度和摩尔体积的非线性波动。Urbach 能量测量和光学带隙显示出 In 2 O 3成分的适度变化。2 B 1g  →  2 B 2g跃迁是由 Cu 2+自旋探针引起的光学吸收光谱中看到的宽的独特吸收带的原因。自旋哈密顿参数随氧化铟含量的非线性变化表明玻璃样品中Cu 2+离子周围的配体场强发生了变化。使用 EPR 和光学吸收光谱数据确定键合参数值,发现它们本质上是离子的。根据FTIR测试,当玻璃中氧化铟的量增加时,一小部分BO 3单元转化为BO 4单元。根据其光学、物理和光谱特性的行为,这些玻璃中的氧化铟似乎在导电、透明度和半导体行为方面产生显着的改变。

更新日期:2024-01-09
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