当前位置: X-MOL 学术Theor. Exp. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Effect of Surface Acidity of Codoped C,S-TiO2 on Their Photocatalytic Properties in the Hydrogen Evolution and Ethanol Oxidation Processes
Theoretical and Experimental Chemistry ( IF 1 ) Pub Date : 2024-01-13 , DOI: 10.1007/s11237-024-09784-x
N. I. Romanovska , G. V. Korzhak , V. M. Grebennikov , O. V. Shulzshenko , P. S. Yaremov , N. I. Ermokhina , P. A. Manoryk

Codoped C,S-TiO2 nanostructures with similar structural and dimensional characteristics and different surface acidity have been obtained using a hydrothermal sol–gel method in the presence thiourea or sulfuric acid. It is established that C,S-TiO2 obtained in the presence of H2SO4 are characterized with acidity of 0.45 mmol/g that results in a high photocatalytic activity in the process of ethanol oxidation. It is shown that C,S-TiO2 obtained in the presence of thiourea, exhibits photocatalytic activity in the reaction of hydrogen evolution under UV and visible light irradiation, which increases with surface acidity decreasing.



中文翻译:

共掺杂C,S-TiO2表面酸性对其析氢和乙醇氧化过程光催化性能的影响

在硫脲或硫酸存在下,采用水热溶胶-凝胶法获得了具有相似结构和尺寸特征以及不同表面酸度的共掺杂C,S-TiO 2纳米结构。确定在H 2 SO 4存在下获得的C,S-TiO 2 的酸度为0.45 mmol/g,这导致在乙醇氧化过程中具有高光催化活性。结果表明,硫脲存在下得到的C,S-TiO 2在紫外和可见光照射下的析氢反应中表现出光催化活性,且随着表面酸度的降低而增加。

更新日期:2024-01-14
down
wechat
bug