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Self-Propagating High-Temperature Synthesis of High-Entropy Carbides in the Gasless Thermal Explosion Mode
Doklady Physical Chemistry ( IF 0.9 ) Pub Date : 2024-01-10 , DOI: 10.1134/s001250162360033x
Yu. S. Vergunova , S. G. Vadchenko , I. D. Kovalev , D. Yu. Kovalev , A. S. Rogachev , M. I. Alymov

Abstract

High-entropy carbides are a new class of inorganic compounds promising for a wide range of applications. A new concept was proposed for the synthesis of powders of high-entropy carbides by self-propagating high-temperature synthesis (SHS) in the gasless thermal explosion mode from previously mechanically synthesized and structured reaction mixtures. For the first time, high-entropy carbides TaTiNbVWC5 and TaNbVMoWC5 were produced by this method, and their crystal structure was determined and compared with those of similar compounds synthesized by sintering.



中文翻译:

无气热爆炸模式自蔓延高温合成高熵碳化物

摘要

高熵碳化物是一类新型无机化合物,具有广泛的应用前景。提出了一种新概念,通过在无气热爆炸模式下自蔓延高温合成(SHS)从先前机械合成和结构化的反应混合物合成高熵碳化物粉末。首次利用该方法制备了高熵碳化物TaTiNbVWC 5和TaNbVMoWC 5 ,测定了它们的晶体结构,并与烧结合成的同类化合物进行了比较。

更新日期:2024-01-10
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