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Yttrium doping improves stability of manganese dioxide cathode for aqueous zinc ion batteries
Solid State Ionics ( IF 3.2 ) Pub Date : 2024-01-23 , DOI: 10.1016/j.ssi.2024.116473
Yue Liu , Song Li , Tong Wei , Mingshan Bai , Zhongsheng Wen , Juncai Sun

Manganese-based oxides are a promising cathode material for aqueous zinc ion batteries. However, structural change and irreversible dissolution of manganese in manganese-based oxides during charging and discharging lead to poor cycling stability, which hinders their large-scale application. Elemental doping is an effective way to regulate the bonding strength and crystal structure of the material. In this paper, YMO materials with nanorod-like structures have been obtained by a hydrothermal method. Y-element doping enhances the stability of the material and improves the electronic and ionic conductivity of the material. The YMO material exhibits excellent electrochemical performance as a cathode material for aqueous zinc ion batteries. The electrode exhibits a high reversible discharge specific capacity of 409.3 mAh g−1 at a current density of 0.1 A g−1, and the electrode capacity hardly decays after 100 charge/discharge cycles, meanwhile, the YMO electrode shows good initial cycling stability even at different charge/discharge current densities. In addition, the YMO electrodes showed long-term cycling stability, with a capacity retention rate of 95.1% after 2000 cycles at a current density of 1 A g−1. The excellent cycling stability of the electrode is mainly due to the improved structural stability of YMO, which is related to the stronger Ysingle bondO bonds acting as anchors in the lattice structure of MnO2. Meanwhile, the strong interaction between doped Y3+ and O2− promotes the storage of H+. Structurally stable electrode materials obtained by optimizing doping elements to modulate bonding energy is an effective way to improve the stability of manganese-based materials.



中文翻译:

钇掺杂提高水系锌离子电池二氧化锰正极的稳定性

锰基氧化物是一种很有前景的水系锌离子电池正极材料。然而,锰基氧化物在充放电过程中的结构变化和锰的不可逆溶解导致循环稳定性差,阻碍了其大规模应用。元素掺杂是调节材料结合强度本文通过水热法获得了具有纳米棒结构的YMO材料Y元素掺杂增强了材料的稳定性,提高了材料的电子和离子电导率。YMO材料作为水系锌离子电池正极材料表现出优异的电化学性能。该电极在0.1 A g -1的电流密度下-1的高可逆放电比容量,并且在100次充放电循环后电极容量几乎不衰减,同时YMO电极甚至表现出良好的初始循环稳定性。在不同的充电/放电电流密度下。此外,YMO电极表现出长期循环稳定性,在1 A g-1。电极优异的循环稳定性主要归功于YMO结构稳定性的提高,这与2晶格结构中更强的Y O键起锚定作用。同时,掺杂的Y 3+和O2−之间的强相互作用+的储存通过优化掺杂元素调节键合能获得结构稳定的电极材料是提高锰基材料稳定性的有效途径。单键

更新日期:2024-01-25
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