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Oxidation Resistance of In Situ Reaction/Hot Pressing Synthesized Ti2AlC–20% TiB2 Composite at 600–900 °C in Air
Acta Metallurgica Sinica-English Letters ( IF 3.5 ) Pub Date : 2024-01-28 , DOI: 10.1007/s40195-023-01647-z
Wenting Wang , Jingjun Xu , Jun Zuo , Ke Ma , Yang Li , Guangqi He , Meishuan Li

The oxidation behavior and kinetics of Ti2AlC–20vol.%TiB2 composite at 600–900 °C in air were investigated. The results showed that the oxidation kinetics of the composite followed a logarithmic law within the given temperature range, which indicated that the composites had excellent oxidation resistance. The selective oxidation of Al in Ti2AlC was greatly enhanced, which facilitated the formation of a continuous and dense protective layer of Al2O3. Meanwhile, the existence of molten B2O3 inhibited the outward diffusion of Ti and inward diffusion of oxygen, which prevented the growth of anatase TiO2 at 600 °C and rutile TiO2 at 700–900 °C. Therefore, the incorporation of TiB2 completely inhibited the abnormally rapid oxidation of bulk Ti2AlC at 600 °C and improved its oxidation resistance at 700–900 °C.



中文翻译:

原位反应/热压合成 Ti2AlC–20% TiB2 复合材料在 600–900 °C 空气中的抗氧化性能

研究了Ti 2 AlC–20vol.%TiB 2复合材料在600–900 °C空气中的氧化行为和动力学。结果表明,在给定温度范围内,复合材料的氧化动力学遵循对数规律,表明复合材料具有优异的抗氧化性能。Ti 2 AlC中Al的选择性氧化大大增强,有利于形成连续致密的Al 2 O 3保护层。同时,熔融B 2 O 3的存在抑制了Ti的向外扩散和氧的向内扩散,从而阻碍了600℃锐钛矿型TiO 2和700~900℃金红石型TiO 2的生长。因此,TiB 2的掺入完全抑制了块体Ti 2 AlC在600℃下异常快速的氧化,并提高了其在700-900℃下的抗氧化性能。

更新日期:2024-01-29
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