: The last decades have witnessed significant advances in the synthesis of bioactive carbohydrates. As in all fields of organic synthesis, the search for more environmentally friendly alternative synthetic methods is a current and expanding concern. Consequently, electrochemical organic synthesis has emerged as an efficient and sustainable methodology. Herein, we present recent developments in the synthesis of glycosides and other carbohydrate derivatives using electrochemical methods. Diverse natural and synthetic O-, S-, and C-glycosides were obtained using new approaches for the electrochemical activation of sugar precursors. The reported derivatives exhibited wide structural diversity on both the sugar moiety and the aglycone, revealing the great potential of the electrochemical methods.

中文翻译：

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糖衍生物的电合成

：过去几十年见证了生物活性碳水化合物合成的重大进展。与有机合成的所有领域一样，寻找更环保的替代合成方法是当前且不断扩大的关注点。因此，电化学有机合成已成为一种有效且可持续的方法。在此，我们介绍了使用电化学方法合成糖苷和其他碳水化合物衍生物的最新进展。使用电化学活化糖前体的新方法获得了多种天然和合成的 O-、S- 和 C-糖苷。报道的衍生物在糖部分和苷元上都表现出广泛的结构多样性，揭示了电化学方法的巨大潜力。