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Shock-wave-induced variation in structural, optical and third-order nonlinear properties of an l-ascorbic acid single crystal
Journal of Applied Crystallography ( IF 6.1 ) Pub Date : 2024-01-19 , DOI: 10.1107/s1600576723010531
Vinod , Anuj Krishna , N. Vijayan , Sachin Yadav , Kiran , Kaphi , Saurabh K. Saini , Rimjhim Yadav , Urvashi Varshney , Subhashree Satapathy , Govind Gupta

The utilization of shock waves plays a pivotal role in the advancement of multiple scientific domains like aerospace, defense, geology, environment, medicine and many more. They serve as essential tools in scientific investigations, enabling the exploration of material behavior under extreme conditions, viz. elevated pressure and temperature. The present study is specifically dedicated to scrutinizing the repercussions of shock waves on an l-ascorbic acid single crystal, to which they were intentionally applied to assess their influence on structural, optical and third-order nonlinearity properties. Powder X-ray diffraction analysis unveiled a discernible overall enhancement in the crystalline quality of the grown crystal following exposure to shock waves. This observation was consistently corroborated by high-resolution X-ray diffraction data, particularly on the (200) crystallographic planes. Furthermore, the optical transmittance of the crystal exhibited a notable increase upon the application of shock waves, while the material's band gap remained unaffected. In parallel, the third-order nonlinearity of the crystal was found to undergo a significant augmentation as a consequence of the shock treatment, as confirmed through Z-scan measurements. These empirical findings unequivocally demonstrate the substantial enhancement in the structural, optical and nonlinear properties of the grown crystal when subjected to shock waves, rendering it well suited for nonlinear optical applications.

中文翻译:

冲击波引起的 L-抗坏血酸单晶的结构、光学和三阶非线性特性的变化

冲击波的利用在航空航天、国防、地质学、环境、医学等多个科学领域的进步中发挥着关键作用。它们是科学研究中的重要工具,能够探索极端条件下的材料行为,即。升高的压力和温度。本研究专门致力于研究冲击波对L-抗坏血酸单晶的影响,并有意将其应用于评估冲击波对结构、光学和三阶非线性特性的影响。粉末 X 射线衍射分析揭示了暴露于冲击波后生长的晶体的晶体质量明显提高。这一观察结果得到了高分辨率 X 射线衍射数据的一致证实,特别是在 (200) 晶面上。此外,在施加冲击波时,晶体的光学透射率显着增加,而材料的带隙不受影响。同时,通过Z扫描测量证实,晶体的三阶非线性由于冲击处理而显着增强。这些经验发现明确证明了生长晶体在受到冲击波时结构、光学和非线性特性的显着增强,使其非常适合非线性光学应用。
更新日期:2024-01-19
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