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Preparation and characterization of high hard and high tough ultrafine WC ceramics containing hybrid graphene and SiC nanowire
Journal of Central South University ( IF 4.4 ) Pub Date : 2024-02-07 , DOI: 10.1007/s11771-023-5506-2
Xue-hui Shen , Nan Xu , Hao Su , Xiang-ping He , Jian-qun He

The aggregation of low-dimensional nanofillers in the host ceramic matrix significantly discounted their reinforcing efficiency. Herein, employing two-dimensional graphene (G) and one-dimensional SiC nanowire (SiCnw), WC-G-SiCnw ceramic composites were prepared through spark plasma sintering. The effects of sintering temperature, soaking time and pressure on the mechanical properties of the WC-based composites were reported. The influence of graphene and SiCnw on the densification, microstructure and mechanical properties of the ceramic composites were investigated. The experimental results demonstrated that excellent mechanical properties were achieved for WC-0.15 wt.% G–0.45 wt.% SiCnw prepared through sintering at 1900 °C for 15 min holding time and 60 MPa pressure, with a hardness of 25.6 GPa, a flexural strength of 1499 MPa and a fracture toughness of 11.6 MPa·m1/2. The toughening mechanisms were mainly the combination of G and SiCnw induced crack deflection, bridging and pullout. This study provided a simple toughening method in developing high-performance ceramic composites.



中文翻译:

杂化石墨烯和SiC纳米线高硬高韧超细WC陶瓷的制备及表征

低维纳米填料在主体陶瓷基体中的聚集显着降低了其增强效率。在此,采用二维石墨烯(G)和一维SiC纳米线(SiC nw),通过放电等离子烧结制备了WC-G-SiC nw陶瓷复合材料。报告了烧结温度、均热时间和压力对WC基复合材料机械性能的影响。研究了石墨烯和SiC纳米线对陶瓷复合材料致密化、微观结构和力学性能的影响。实验结果表明,在1900 ℃、15 min、60 MPa压力下烧结制备的WC-0.15 wt.% G–0.45 wt.% SiC纳米线具有优异的力学性能硬度为25.6 GPa,弯曲强度为1499 MPa,断裂韧性为11.6 MPa·m 1/2。增韧机制主要是G和SiC纳米线诱导裂纹偏转、桥联和拔出的组合。这项研究为开发高性能陶瓷复合材料提供了一种简单的增韧方法。

更新日期:2024-02-08
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