Liquid metal as an efficient protective layer for lithium metal anodes in all-solid-state batteries,Carbon Energy

当前位置： X-MOL 学术 › Carbon Energy › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Liquid metal as an efficient protective layer for lithium metal anodes in all-solid-state batteries
Carbon Energy ( IF 20.5 ) Pub Date : 2024-02-15 , DOI: 10.1002/cey2.462
Shiqiang Zhou _{1,

2} , Mengrui Li _{1,

2} , Peike Wang _{1,

2} , Lukuan Cheng _{1,

2} , Lina Chen _{1,

2} , Yan Huang _{1,

2,

3} , Boxuan Cao _{1,

2,

3} , Suzhu Yu _{1,

2} , Qingju Liu ₄ , Jun Wei _{1,

2,

3}

Affiliation

Lithium metal batteries with inorganic solid-state electrolytes have emerged as strong and attractive candidates for electrochemical energy storage devices because of their high-energy content and safety. Nonetheless, inherent challenges of deleterious lithium dendrite growth and poor interfacial stability hinder their commercial application. Herein, we report a liquid metal-coated lithium metal (LM@Li) anode strategy to improve the contact between lithium metal and a Li₆PS₅Cl inorganic electrolyte. The LM@Li symmetric cell shows over 1000 h of stable lithium plating/stripping cycles at 2 mA cm⁻² and a significantly higher critical current density of 9.8 mA cm⁻² at 25°C. In addition, a full battery assembled with a high-capacity composite LiNbO₃@LiNi_0.7Co_0.2Mn_0.1O₂ (LNO@NCM721) cathode shows stable cycling performance. Experimental and computational results have demonstrated that dendrite growth tolerance and physical contact in solid-state batteries can be reinforced by using LM interlayers for interfacial modification.

更新日期：2024-02-17

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文

全部期刊列表>>