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Metal-organic frameworks as potential catalysts for biodiesel production and biomass conversion: Mechanism and characteristics
Industrial Crops and Products ( IF 5.9 ) Pub Date : 2024-02-21 , DOI: 10.1016/j.indcrop.2024.118232
Thanh Tuan Le , Prabhakar Sharma , Huu Son Le , Huu Cuong Le , Duc Trong Nguyen Le , Dao Nam Cao , Thanh Hai Truong , Viet Dung Tran

This comprehensive assessment examines the key challenges confronting the transportation sector, a major source of greenhouse gas emissions. These issues include rising fuel costs and declining reserves. Although electric mobility is becoming more popular in light-duty transportation, heavy-duty trucks continue to rely heavily on diesel engines. Biofuels are the subject of extensive research as both a financially viable and environmentally conscious alternative. Biodiesel derived from animal fats and vegetable oils is widely recognized for its natural decomposition, low toxicity, low pollutant emissions, and renewable properties. Catalysts aid in the chemical transformation of biomass, an important renewable energy source around the world. Solid acid catalysts are becoming increasingly important in improving the quality of biomass. This study analyzes the ability of metal-organic frameworks (MOFs), which are hybrid nanoporous materials, to act as catalysts in biomass conversion and biodiesel production. MOFs offer exceptional performance attributes, including large surface areas and customizable pore architectures, making them highly versatile for various applications. The review analyzes the role of MOF-based catalysts in accelerating biomass conversions and biodiesel synthesis, focusing on their structural properties, benefits, and challenges. This work provides useful insights into the significance of MOFs. It emphasizes MOFs as critical catalysts for promoting green chemistry practices and advancing the paradigm of sustainable energy production.

中文翻译:

金属有机框架作为生物柴油生产和生物质转化的潜在催化剂:机制和特点

这项综合评估探讨了作为温室气体排放主要来源的交通部门所面临的主要挑战。这些问题包括燃料成本上升和储量下降。尽管电动汽车在轻型运输中越来越受欢迎,但重型卡车仍然严重依赖柴油发动机。生物燃料作为一种经济上可行且具有环保意识的替代品而成为广泛研究的主题。源自动物脂肪和植物油的生物柴油因其自然分解、低毒、低污染物排放和可再生特性而被广泛认可。催化剂有助于生物质的化学转化,生物质是世界各地重要的可再生能源。固体酸催化剂在提高生物质质量方面变得越来越重要。本研究分析了金属有机框架(MOF)(一种混合纳米多孔材料)在生物质转化和生物柴油生产中作为催化剂的能力。MOF 具有卓越的性能属性,包括大表面积和可定制的孔结构,使其具有高度通用性,适用于各种应用。该综述分析了 MOF 基催化剂在加速生物质转化和生物柴油合成中的作用,重点关注其结构特性、优点和挑战。这项工作为理解 MOF 的重要性提供了有用的见解。它强调 MOF 作为促进绿色化学实践和推进可持续能源生产范式的关键催化剂。
更新日期:2024-02-21
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