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Improvement of film quality and solar cell properties of perovskite by the addition of N-benzylhydroxylamine
Applied Physics Express ( IF 2.3 ) Pub Date : 2024-03-07 , DOI: 10.35848/1882-0786/ad2a05
Keisuke Nagasawa , Takeshi Sano , Viet CHAU NGUYEN , Yutaka Okuyama , Yuya Sayama , Ryosuke Oikawa , Keigo Hoshi , Takayuki Chiba , Junji Kido

In this study on perovskite solar cells (PVSCs), we incorporate N-benzylhydroxylamine (N-BzHoA) as an additive into the precursor solution. The addition of N-BzHoA suppressed the formation of unwanted PbI2 and δ-phase perovskite without affecting the band gap, confirming uniform and large grains in the perovskite film. The fabricated inverted PVSCs exhibited remarkably improved properties compared to the control device, with a power conversion efficiency of 17.49%, reduced hysteresis, and more than 89% retention of the initial capacity after 100 h of light exposure. Thus, this study highlights the effectiveness of N-BzHoA as an effective additive for inverted PVSCs.

中文翻译:

添加N-苄基羟胺改善钙钛矿薄膜质量和太阳能电池性能

在这项关于钙钛矿太阳能电池(PVSC)的研究中,我们将 N-苄基羟胺(N-BzHoA)作为添加剂加入到前驱体溶液中。 N-BzHoA的添加抑制了不需要的PbI 2和δ相钙钛矿的形成,而不影响带隙,证实了钙钛矿薄膜中均匀且大的晶粒。与对照器件相比,所制备的倒置PVSC表现出显着改善的性能,功率转换效率为17.49%,滞后现象减少,并且在光照100小时后初始容量保留率超过89%。因此,这项研究强调了 N-BzHoA 作为倒置 PVSC 的有效添加剂的有效性。
更新日期:2024-03-07
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