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Effect of δ–ferrite and strain-induced martensite on hydrogen embrittlement of STS 308 L and STS 316 L all-weld metals
Corrosion Science ( IF 8.3 ) Pub Date : 2024-03-07 , DOI: 10.1016/j.corsci.2024.111977
Donghyeon Choi , Jimin Nam , Byungrok Moon , Sourav Kr. Saha , Jaeseok Yoo , Jong Min Park , Kwang Hee Yun , Namhyun Kang

The susceptibility of multipass flux-cored arc welds of STSs 308 L and 316 L to hydrogen embrittlement (HE) was investigated at various temperatures. Cracks predominantly initiated and propagated along the δ-ferrite in the interdendritic region at 25 °C. δ-ferrite served as preferred hydrogen trap sites, and the δ/γ boundary became the stress concentration site. At −100 °C, STSs 308 L and 316 L exhibited high susceptibility to HE owing to strain-induced martensite formation, providing additional hydrogen trap sites and dislocation accumulation. Despite strain-induced martensite actively transformed at −196 °C, the HE disappeared owing to the sluggish diffusion of hydrogen to stress-concentrated areas.

中文翻译:

δ-铁素体和应变诱导马氏体对 STS 308 L 和 STS 316 L 全焊缝金属氢脆的影响

在不同温度下研究了 STS 308 L 和 316 L 多道药芯焊丝电弧焊对氢脆 (HE) 的敏感性。 25 °C 时,裂纹主要沿着枝晶间区域的 δ 铁素体引发和扩展。 δ-铁素体是优选的氢陷阱位点,δ/γ边界成为应力集中位点。在-100 °C 时,STS 308 L 和 316 L 由于应变诱导马氏体形成而表现出对 HE 的高敏感性,提供了额外的氢陷阱位点和位错积累。尽管应变诱导马氏体在-196°C 时发生积极转变,但由于氢向应力集中区域的缓慢扩散,HE 消失了。
更新日期:2024-03-07
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