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Exploring mechanism of corrosion inhibition of WE43 and AZ31 alloys by aqueous molybdate in Hank’s solution by multisine impedimetric monitoring
Corrosion Science ( IF 8.3 ) Pub Date : 2024-03-07 , DOI: 10.1016/j.corsci.2024.111979
Maria A. Osipenko , Jakub Karczewski , Michał Dominów , Marta Prześniak-Welenc , Jacek Gurgul , Iryna I. Kurilo , Jacek Ryl , Dzmitry S. Kharytonau

The concept of utilizing multisine dynamic electrochemical impedance spectroscopy to monitor effectiveness of a model molybdate inhibitor for AZ31 and WE43 Mg alloys is proposed. The corrosion kinetics and instantaneous values of inhibition efficiency () of molybdate at concentrations up to 150 mM were examined. The inhibitor provides inhibition in Hank’s solution at concentrations starting from ca. 25 mM, with the of about 90%. These data together with results of the surface analysis allowed to propose the mechanism of the corrosion inhibition of AZ31 and WE43 Mg alloys by aqueous molybdate in Hank’s solution.

中文翻译:

通过多正弦阻抗监测探索汉克溶液中钼酸水溶液对WE43和AZ31合金的缓蚀机理

提出了利用多正弦动态电化学阻抗谱监测 AZ31 和 WE43 镁合金钼酸盐抑制剂模型有效性的概念。检查了浓度高达 150 mM 的钼酸盐的腐蚀动力学和抑制效率 () 的瞬时值。该抑制剂在 Hank's 溶液中提供抑制作用,浓度从 ca 开始。 25 mM,约90%。这些数据与表面分析结果一起提出了 Hank 溶液中钼酸盐水溶液对 AZ31 和 WE43 镁合金的腐蚀抑制机制。
更新日期:2024-03-07
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